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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 196 (1992), S. 101-106 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Orientierung (Neigungswinkel ϕ) von thermotropen Flüssigkristallen (LC) an der Grenzfläche zu polymerbeschichteten Substraten wird nicht nur durch den numerischen Wert der Oberflächenspannung \documentclass{article}\pagestyle{empty}\begin{document}${\rm \gamma }_{\rm S} {\rm }\left( {{\rm \gamma }_{\rm S} {\rm = \gamma }_{\rm S}^{\rm d} {\rm + \gamma }_{\rm S}^{\rm p} } \right)$\end{document} bestimmt. Das Verhältnis zwischenden dispersiven und polaren Anteilen an \documentclass{article}\pagestyle{empty}\begin{document}${\rm \gamma }_{\rm S} {\rm }\left( {{\rm \gamma }_{\rm S}^{\rm d} {\rm : \gamma }_{\rm S}^{\rm p} } \right)$\end{document} beeinflußt ebenfalls die Orientierung der LC-Moleküle an der Substratoberfläche. Als Polymere wurden ein Polyimid und ein Midgruppenhaltiges Styrol/Maleinsäureanhydrid-Copolymeres verwendet.
    Notes: The orientation (tilt angle ϕ) of thermotropic liquid crystals (LC) on the interface to a polymer-coated surface is not only determined by the numerical value \documentclass{article}\pagestyle{empty}\begin{document}${\rm \gamma }_{\rm S} {\rm }\left( {{\rm \gamma }_{\rm S} {\rm = \gamma }_{\rm S}^{\rm d} {\rm + \gamma }_{\rm S}^{\rm p} } \right)$\end{document} of the substrate surface tension. However, the ratio between the dispersive and the polar part of \documentclass{article}\pagestyle{empty}\begin{document}${\rm \gamma }_{\rm S} {\rm }\left( {{\rm\gamma }_{\rm S}^{\rm d} {\rm : \gamma }_{\rm S}^{\rm p} } \right)$\end{document} also influences the LC orientation on the substrate surface. A polyimide and an amide-modified styrene/maleic anhydride copolymer were used as polymers.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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