ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Sixteen acetylenic amine oxides (5a-p) were prepared by the oxidation of the corresponding tertiary amines (4a-p) with m-chloroperbenzoic acid. The N-oxides are thermally unstable and undergo a rearrangement when stirred in an inert solvent yielding O-allenyl hydroxylamines (6). The rearrangement proceeds by an intramolecular cyclic mechanism.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19893310203
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