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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 4324-4332 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report on a deuteron NMR study of quadrupolar splittings and spin-lattice relaxation times T1Q and T1Z as a function of temperature and at two different Larmor frequencies in the columnar phase of hexakis(n-hexyloxy)triphenylene (HAT6). The additive potential method is used to model the quadrupolar splittings, from which the potential of mean torque is parameterized, and the order parameter tensor for an "average" conformer is determined. The small-step rotational diffusion model is used to find the rotational diffusion constants D(parallel) and D⊥ for the spinning and tumbling motions of the molecular core. It is found that D⊥ is slightly larger than D(parallel) in contrast with the findings in calamitic liquid crystals. The decoupled model of Dong for correlated internal rotations in the end chains is used for the first time in a discotic liquid crystal. Both jump constants for one- and three-bond motions are nearly independent of temperature, while the jump constant for two-bond motion is thermally activated. The rotational speeds D(parallel) and D⊥ are some two orders of magnitude slower than a typical charge hopping frequency between the aromatic cores of adjacent molecules in the columns. Thus, to a migrating charge, the "lattice" appears static with disorder being due to the instantaneous displacement of the cores with respect to each other. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 5731-5733 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High-quality InGaN/GaN multiple-quantum wells (MQWs) with different In fractions varying from 0.04 to 0.30 have been grown on Ga-polarity GaN by N2 plasma-assisted molecular-beam epitaxy (rf-MBE). High-resolution x-ray diffraction results have indicated that the high interface quality and good reproducibility of the InGaN QW have been achieved. Photoluminescence spectra reveals the superior and intense luminescence properties of InGaN MQWs from ultraviolet (∼388 nm) to green-yellow (∼528 nm) range. We have shown that the Ga-polarity GaN underneath is the key parameter for the successful growth of InGaN MQWs by rf-MBE. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 4165-4170 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The streaming induced in a short vertical liquid column (L/R≤1, L: length, R: radius) by the vibration of one of the supporting end walls has been utilized in this novel study. Vibration essentially drives a surface flow in the zone away from the vibrating wall, with the return flow in the bulk towards the wall. Preliminary measurements of the surface streaming velocity show that it increases with the frequency and amplitude of vibration and the zone length, and decreases with the viscosity of the zone liquid. This controlled surface streaming has been employed to balance an opposing, steady thermocapillary flow in a model half-zone of silicone oil. In addition to the evidence gathered through flow visualization, temperature measurements in the zone reveal that the radial temperature gradients set up by the thermocapillary flow are weakened/offset by this balancing.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 7549-7553 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An experimental method is described to measure the time-resolved fluorescence spectrum of a dye in a liquid subjected to shock wave, uniaxial strain compression. Data are reported for rhodamine-6G in ethanol solution shocked to 19 kbar and compared to hydrostatic measurements [Appl. Opt. 24, 2779 (1985)]. Unlike the hydrostatic measurements, a continuous red shift of the fluorescence band with pressure was observed over the entire pressure range. In addition, the shock data show a larger shift rate than the hydrostatic data below 2.6 kbar and a comparable rate above this pressure, resulting in an overall larger shift with pressure. Implications of the present results for examining microscopic response of shocked liquids are discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 583-585 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Results of shock-wave experiments to examine ruby R-line shifts for uniaxial strain compression along the crystal a axis are summarized and compared with previous c-axis results [P. D. Horn and Y. M. Gupta, Phys. Rev. 39, 973 (1989)]. The present results show that R1-line shift with compression depends on both nonhydrostatic stresses and crystal orientation. Hence, pressure determination using R1-line shifts in a nonhydrostatic environment can lead to errors. In contrast, the R2-line shift depends only on density compression and is independent of nonhydrostatic stresses and crystal orientation. These findings suggest the use of R2-line shifts for pressure calibration under nonhydrostatic loading conditions.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 12 (2000), S. 2976-2989 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The postulate of local isotropy (PLI) is tested in a wind tunnel uniform shear flow in which the Reynolds number is varied over the range 100≤Rλ≤1, 100(6.7×102≤Rl≤6.3×104). The high Rλ is achieved by using an active grid [Mydlarski and Warhaft, J. Fluid Mech. 320, 331 (1996)] in conjunction with a shear generator. We focus on the increments of the longitudinal velocity fluctuations in the direction of the mean shear. PLI requires that odd order moments of these quantities approach zero as Rλ→∞. Confirming the lower Reynolds number measurements of Garg and Warhaft [Phys. Fluids 10, 662 (1998)], we show that the skewness of ∂u/∂y decreases as Rλ−0.5 (with a value of 0.2 at Rλ∼1000). Although the decrease is slower than classical scaling arguments suggest, the result is consistent with PLI, indicating a negligible value at high Rλ. However, the normalized fifth moment, 〈(∂u/∂y)5〉/〈(∂u/∂y)2〉5/2, is of order 10, and shows no diminution with Reynolds number, while the normalized seventh moment increases with Rλ. These dissipation range results are inconsistent with PLI. Within the inertial subrange we show that all the odd order moments of the increments of Δu(y) are nonzero, exhibiting scaling ranges. Here, the skewness structure function has a value ∼0.5 indicating that in the inertial subrange significant anisotropy is evident even at the third moment level. Fifth- and seventh-order inertial subrange skewness structure functions are of order 10 and 100, respectively. The results show that PLI is untenable, both at dissipation and inertial scales, at least to Rλ∼1000, and suggest it is unlikely to be so even at higher Reynolds numbers. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 13 (2001), S. 1532-1533 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 14 (2002), S. 370-381 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The scaling exponents of the longitudinal structure function, 〈Δuxn〉 and two different transverse structure functions: the longitudinal velocity, u, measured in the transverse, y direction (the direction of the mean shear), 〈Δuyn〉, and the transverse velocity v, measured in the flow direction, x, 〈Δvxn〉, up to n=8, are studied in an approximately uniform shear flow [Shen and Warhaft, Phys. Fluids 12, 2976 (2000)], as well as in decaying (shearless) grid turbulence. Results, for low Reynolds numbers (Rλ∼100–200) and high Reynolds numbers (Rλ∼800–1000) are compared. It is shown that at high Rλ, the scaling exponents of 〈Δuyn〉, ζu(y)(n), are the same as those of the longitudinal structure function exponents, ζu(x)(n), for both even and odd values of n. The observation that ζu(y)(n)∼ζu(x)(n) (n odd) is in violation of the postulate of local isotropy (PLI) and implies that the anomalous scaling (departures from the Kolmogorov 1941 scaling) is fully captured by the anisotropy since these odd moments are zero in isotropic turbulence. In the low Rλ shear flow ζu(y)(n)〈ζu(x)(n) suggesting that here this transverse component has not yet reached its high Rλ limit. In the absence of shear, ζu(y)(n)∼ζu(x)(n) at high Rλ (similar to the shear case but with the odd moments of 〈Δuyn〉 equal to zero). Similarly, at low Rλ, ζu(y)(n)〈ζu(x)(n). On the other hand, the scaling exponent of the v structure function (〈Δvxn〉), ζv(x)(n), was lower than that of ζu(x)(n), even at high Rλ. The results are related to numerical, and other laboratory studies. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 14 (2002), S. 2432-2438 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Structure functions to order 8 are determined from the longitudinal and transverse velocity fluctuations measured at a single point in high Reynolds number laboratory shear flow. We examine the relationship between mixed structure functions (which are explicitly zero in isotropic flow), and those of the longitudinal and transverse structure functions. Our results confirm recent findings using SO(3) symmetry decomposition [S. Kurien and K. R. Sreenivasan, Phys. Rev. E 62, 2206 (2000)] that show that the mixed structure functions have larger scaling exponents than those of the single component structure functions, i.e., the j=2 anisotropic sector structure function scaling exponent is greater than that of the j=0 isotropic sector. However, we also show that the ratio of the j=2 to j=0 sector scaling exponents systematically decreases with increasing order, suggesting that at higher orders there is persistence of anisotropy at the smallest scales. Difficulties in the analysis due to the difference in scaling exponents of the transverse and longitudinal structure functions are addressed. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 79 (2001), S. 1599-1601 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Time-resolved photoluminescence measurements at 5 K were performed to study the optical properties of InGaN/GaN multiple-quantum wells (MQWs) grown by plasma-assisted molecular-beam epitaxy (rf-MBE). Stimulated-emission (SE) phenomena by optical pumping were observed under the high-excitation density from the InGaN/GaN MQW samples with the In composition varying from 0.04 to 0.16. It was found that the threshold density for SE phenomena strongly depended on the In composition, where the lowest threshold density was 69 μJ/cm2 from our samples. Our results show a potential of rf-MBE technique for the future optical device applications. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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