ISSN:
1432-5225
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
,
Maschinenbau
Notizen:
Summary 1H NMR analysis of the reaction of lignin model p-quinone methides with aliphatic alcohols, phenols and p-hydroxybenzyl alcohols in chloroform solution has demonstrated a pronounced predominance of non-cyclic benzyl alkyl ethers over benzyl aryl ethers in the mixture of products, as a result of faster addition of alcohols than phenols. In the case of the simplest p-quinone methides, the only competing reaction seems to be a stereoselective isomerization into E-p-hydroxystyrenes.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00226079
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