ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The rate constant k4 has been measured at 268°, 298°, and 334° K for the reaction CH2O + 2OH → CO + 2H2O relative to that for OH + OH (k2) by competition experiments in a discharge flow tube using mass-spectrometric analysis. Based on k2 = 2.24 × 10-12cm3/molec·sec at 298°K and E2 = 4 kJ/mol, k4 = (6.5 ± 1.5) × 10-12cm3/molec·sec at 298°K and E4 = (6 ± 2)kJ/mol.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550100509
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