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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 67 (1978), S. 127-138 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Oxygen Fugacity measurements were carried out on chromites from the Eastern Bushveld Complex (Maandagshoek) and are compared with former measurements on chromites from the western Bushveld Complex (Zwartkop Chrome Mine). These results together with those of Hill and Roeder (1974) yield the following conditions of formation for the massive chromitite layers: Western Bushveld Complex (Zwartkop Chrome Mine) $$\begin{gathered} Layer{\text{ }}T(^\circ C) p_{O_2 } (atm) \hfill \\ LG3{\text{ 1160}} - {\text{1234 10}}^{ - {\text{5}}} - 10^{ - 7.6} \hfill \\ LG4{\text{ 1175}} - {\text{1200 10}}^{ - 6.35} - 10^{ - 7.20} \hfill \\ LG6{\text{ 1162}} - {\text{1207 10}}^{ - 6.20} - 10^{ - 7.50} \hfill \\ \hfill \\ \end{gathered} $$ Eastern Bushveld Complex (Farm Maandagshoek) $$\begin{gathered} {\text{LXI 1115}} - {\text{1150 10}}^{ - 7.80} - 10^{ - 8.80} \hfill \\ ( = {\text{Steelpoort Seam)}} \hfill \\ {\text{LX 1125 10}}^{ - 8.25} \hfill \\ {\text{V 1120 10}}^{ - 8.55} \hfill \\ {\text{LII 1120 10}}^{ - 8.0} - 10^{ - 8.60} \hfill \\ \end{gathered} $$ The comparison of the data shows, that the chronitite layers within each particular sequence were formed under approximately identicalp o 2- andT-conditions. The chromites from the western Bushveld Complex, however, were formed at higher temperatures and higher oxygen fugacities than the chromites from the eastern Bushveld Complex. Fromp o 2-T-curves of disseminated chromites and the temperatures derived above, the following conditions of formation for the host rocks were obtained: Western Bushveld Complex $$T = 1200^\circ {\text{C; }}p_{{\text{o}}_{\text{2}} } = 10^{ - 7.25} - 10^{ - 7.50} $$ Eastern Bushveld Complex $$T = 1125^\circ {\text{C; }}p_{{\text{o}}_{\text{2}} } = 10^{ - 8.50} - 10^{ - 9.25} $$ Consequently, the host rocks in the Zwartkop-Chrome-Mine, were formed under higher temperatures and higher oxygen fugacities than the host rocks at Maandagshoek. The rock sequence in the Zwartkop-Chrome-Mine therefore originated in an earlier stage of the differentiation of the Bushveld magma. Comparison of the chromites from the host rocks with the chromites from massive layers supports Ulmer's (1969) thesis that an increase of the oxygen fugacity is responsible for the formation of massive chromitite layers. The values in this investigation show that increases of only about 0.5–1.0 log units are necessary to enhance chromitite layer formation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 44 (1993), S. 48-56 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The atmospheric corrosion of copper and bronze within the UN/ECE Exposure Programme. Intermediate report after 4 years of exposureAccompanied by an extensive measuring programme for environmental data, copper (DIN 1787) and bronze samples (DIN 1705) were exposed at 39 test sites in 14 countries and examined afterwards. Measured were the weight change, the mass loss (after pickling of the corrosion products), the colour changes (trichromatic colorimetry), the chemical composition of the corrosion products (Debye-Scherrer), the layer thickness (eddy-current method), and the roughness of the weathered surface (perthometer). The corrosion data are related with the environmental data, especially the concentration of sulfur dioxide, the relative humidity and the conductivity of precipitations.
    Notes: Begleitet von einem umfassenden Meßprogramm für Umweltdaten wurden an 39 Stationen in 14 Ländern Kupfer- (DIN 1787) und Bronzeproben (DIN 1705) exponiert und anschließend untersucht. Gemessen wurden die Gewichtsveränderung, der Massenverlust (nach Abbeizen der Korrosionsschichten), die Farbveränderung (Dreibereichsverfahren), die chemische Zusammensetzung der Korrosionsprodukte (Debye-Scherrer), die Schichtdicke (Wirbelstromverfahren) sowie die Rauhigkeit der bewitterten Oberfläche (Perthometer). Die Korrosionsdaten stehen dabei im Zusammenhang mit den Umweltdaten, insbesondere der Schwefeldioxidkonzentration, der Leitfähigkeit der Niederschläge und der Luftfeuchtigkeit.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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