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Formation of Chiral N-Oxides from 2-Azabicyclo[3.3.0]octanes (1999)

Günter Aurich, Hans ; Soeberdt, Michael ; Harms, Klaus

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 1249-1252

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ISSN: 1434-193X

Keywords: Amino alcohols ; Amine N-oxides ; Asymmetric synthesis ; Hydrogen bonds ; Structure determination ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: -Enantiopure 2-azabicyclo[3.3.0]octanes 1a-d and ent-1e were oxidized with mCPBA to provide either diastereomeric pairs of N-oxides (2a/3a and 2b/3b) or diastereomerically pure compounds (2c,d and ent-2e). The structure of compounds 2a and ent-2e was confirmed by an X-ray study. The factors that affect the oxidation process are discussed.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

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