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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 1167-1179 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyethylene was drawn at temperatures ranging from 30° to 60°C in aggressive and nonaggressive environments. Fibrillation was found to occur in the aggressive environment, and this effect increased with temperature. The temperature effect was more prominent at lower strain rates. Thin films drawn in aggressive environments deformed inhomogeneously. Again, this effect was found to increase with increasing temperatures. Single crystal deformation was also found to be inhomogeneous, and “solvation” of the amorphous surface layer occurred in the presence of the aggressive environment. Infrared measurements of sorption under different loads indicated that there is an increase in the amount of sorbed materials with increasing load. Dynamic mechanical studies revealed the intracrystalline regions to be affected preferentially.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 1533-1559 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An enquiry is presented into the nature and origin of thermoreversible gelation of poly(vinyl chloride) (PVC). In line with a previous paper it is demonstrated by direct x-ray diffraction evidence that the origin of the gelation is crystallization, and that this crystallinity can be conspicuously apparent even for the usual technological polymer. In addition some unusual diffraction effects become apparent such as do not obviously follow from existing notions of the PVC structure. Combined infrared dichroism and x-ray studies revealed that these new effects are attributable to a two-component nature of the crystallinity where the components are distinguished by their orientation behavior, lateral extension, and possibly morphology of the crystallites. Some of the crystals orient with their a axes (type A crystals) and some with their c axes (type B crystals) along the stretch direction. Other more complex orientability differences are also manifest during film formation. Crystals B are smaller, and are believed to correspond to the network forming junctions, hence to fringed micellar crystals. Crystals A have a less evident connection with the network and are hypothesized to be of lamellar character, the behavior of which is closely simulated by lamellar crystal additives (stabilizer crystals). High-temperature x-ray work revealed no melting of crystals even in the temperature range where endotherms appear in the thermograms.
    Additional Material: 21 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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