ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The mass spectral behavior of trans-1-arylsulfonyl-2-arylsulfenyl-propenes, trans-1-arylsulfonyl-2-arylsulfinyl-propenes and trans-1, 2-(arylsulfonyl)-propenes was examined. A Smiles type rearrangement was present in the sulfonyl-sulfides, but was completely absent in the trans-1-arylsulfonyl-2-arylsulfinyl-propenes and trans-1, 2-(arylsulfonyl)-propenes. Vinyl migration to the sulfone oxygen predominates over aryl migration in all of the compounds studied. The mass spectra of the cis and trans isomers of 1-p-tolylsulfenyl-2-p′-tolysulfonyl-propene and 1, 2-(p-tolylsulfonyl)-propene are also described.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210120608
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