ISSN:
1600-5724
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
Application of the Rayleigh criterion for the limit of resolution of a simple lens with axial illumination leads to the value 0.61λ. In two-dimensional electron density maps based on X-ray data, the limit of resolution has been considered to be 0.61 dmin, the counterpart of the optical case, and in three-dimensional maps 0.715 dmin. It is shown here that point atoms separated by these distances are not resolved in two- and three-dimensional electron density maps. Such maps are amplitude functions rather than intensity functions as in the optical case. Application of the Rayleigh criterion to the three-dimensional amplitude function for point atoms leads to a value of 0.917 dmin, for the limit of resolution in three-dimensional electron density maps. This result is confirmed by superposing both analytic and numeric functions for point atoms and numeric functions for real atoms with B = 0 and 10 Å2. Finally, some implications of diffraction effects in X-ray structure analysis are considered.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108767384000507
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