ISSN:
0899-0042
Keywords:
hydrobenzoin
;
asymmetric oxidation
;
osmium tetroxide
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The chiral biphenyl-containing diamine 1 complexed with OsO4 oxidized trans-stilbene at -80°C to (+)-(1R;2R)-1,2-diphenyl-1,2-ethanediol in high enantiomeric excess. On the other hand, (R)- or (S)-2,2'-bis(dimethylamino)-6,6'-dimethylbiphenyl proved to be ineffective in promoting oxidation. © 1992 Wiley-Liss, Inc.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/chir.530040507
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