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Thermal decomposition of 2,2-propane-d2. CH3CDCH3 radical isomerization (1980)

Szirovicza, L. ; Sziláagyi, I.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 12 (1980), S. 113-122

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The decomposition of CH3CD2CH3 was studied from 713 to 853 K at pressures of 98-466 torr. The values of k1/k2 = 2.08 ± 0.05 and k3/k4 = 2.04 ± 0.66 were found independent of temperature by measuring the ratios of CH4/CH3D and CH3CHD2/CH3CD3, respectively, for the following reactions:. Isomerization of CH3CDCH3 was detected by measuring CHDCH2 formed from the isomerized radical. The expression of k21/k22 was found to be where k21 and k22 are the rate constants of. The results and conclusions are discussed and compared with previous works.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550120205

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