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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    International journal of cosmetic science 16 (1994), S. 0 
    ISSN: 1468-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: The phase inversion emulsification is a convenient method of preparing fine-disperse and long-term stable oil-in-water emulsions, which are stabilized with nonionic emulsifiers. On the basis of EACN-values (equivalent alkane carbon numbers) the calculation of phase inversion in concentrates (CAPICO) is possible, which yields emulsifier and oil mixing ratios corresponding to a given phase inversion temperature (PIT). The CAPICO-method is illustrated for the example of a cosmetic oil-in-water lotion containing an oil mixture, glyceryl monostearate and a fatty alcohol ethoxylate. Of special interest is the influence of silicone oils on the PIT. At a constant emulsifier oil ratio the complete phase behaviour of this emulsion system is represented in a temperature/water content graph. Optimum emulsification results are obtained if during PIT emulsification a microemulsion or a lamellar phase is passed. The emulsions were characterized by particle sizing, and emulsion stability against sedimentation was evaluated by ultrasonic velocity changes. A fine-disperse and long-term stable oil-in-water emulsion was prepared by a time and energy-saving two-step hot-cold process.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    International journal of cosmetic science 12 (1990), S. 0 
    ISSN: 1468-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Oil-in-water emulsions stabilized with nonionic emulsifiers change to water-in-oil emulsions as the temperature rises when the hydrophilic and lipophilic properties of the mixed emulsifier are just balanced. Preparation above the phase inversion temperature followed by rapid cooling yields emulsions that exhibit very fine droplet size and extreme long-term stability. Cosmetic emulsions were prepared by this phase inversion temperature (PIT) method using typical raw materials such as polar oils, e.g. decyl oleate, 2-octyl dodecanol or isopropyl myristate, and nonionic emulsifiers, e.g. ceteareth-12 or polyoxyethylene eicosyl/docosyl ether combined with cetostearyl alcohol as a co-emulsifier. The phase inversion temperature was measured as a function of the oil polarity and the concentration of mixed emulsifier. The relationship between phase inversion temperature, droplet size and emulsion stability was investigated. In addition, self-bodying agents such as cetostearyl alcohol or monoglycerides were added to these thin, fine disperse emulsions to adjust the consistency. The influence of these ingredients on phase inversion temperature, droplet size, yield value and emulsion stability was studied.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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