ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and X-Ray Examination of Ba2Ni(N3)6 · 3 H2OBa2Ni(N3)6 · 3 H2O has been prepared by the reaction of an aqueous solution of Ba(N3)2 with basic nickel azide. The crystals are green, the lattice constants are: a = 7.09 Å, b = 7.09 Å, c = 16.30 Å, α = 74.58°, β = 105.42°, γ = 97.10°, N = 2. Optical spectra point to an octahedral microsymmetry of the azide ions around nickel.
Notes:
Ba2Ni(N3)6 · 3 H2O bildet sich aus wäßrigen Lösungen von Ba(N3)2 nach Reaktion mit basischem Nickelazid in Form kleiner grüner Kristalle. Die Gitterkonstanten betragen: a = 7,09 Å, b = 7,09 Å, c = 16,30 Å, α = 74,58°, β = 105,42°, γ = 97,10°, Z = 2. Spektroskopisch wurde oktaedrische Mikrosymmetrie der Azidionen um Nickel nachgewiesen.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19764240214
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