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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 88 (1984), S. 6727-6732 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 395-398 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Small angle neutron scattering (SANS) has been used to establish the dispersed droplet character of a class of pseudo-three-component oil/water (o/w) microemulsions which can be cooled continuously into the glassy state without either crystallization or microemulsion destabilization. SANS of toluene microemulsions at low volume fractions (∼0.5%) of toluene indicate a droplet radius of 270±10 A(ring). At normal concentrations (∼33 vol % oil), the droplet size cannot be determined precisely but the presence of a droplet state of small polydispersity is established for toluene, p-xylene, benzene, CS2, and CCl4 by the presence of a sharp peak in the scattered neutron intensity vs Q plots. Average interdroplet separations range from 200 to 300 A(ring), implying average radii of ∼125 A(ring). Such radii are consistent with freeze–fracture electron microscope studies of the same or similar systems. Variable temperature studies on toluene microemulsions during both cooling and warming cycles in the temperature range ambient to 100 K, show only minor (∼10%) changes in the interdroplet separation down to 220 K at which temperature diffusion through the viscous matrix phase becomes too slow to permit further emulsion structure changes on the time scale of the cooling experiment. The origin, and some possible exploitations, of this unusual stability against temperature change are discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 2732-2737 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Small-angle neutron scattering (SANS) measurements have been performed in heavy water solutions of 2-butoxyethanol as a function of concentration and temperature. The results indicate that there exist some alcohol aggregation above a narrow concentration range (x=0.015–0.02, where x is the alcohol molar fraction) and the size of the aggregates increases with temperature taking a maximum value at a composition close to the critical concentration. The analysis of the size and of the absolute scattered intensity at q=0(I0) in terms of a microscopic model of aggregation, as well as the indications from other experiments, suggest that these aggregates are micelle-like structures.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    The @journal of eukaryotic microbiology 23 (1976), S. 0 
    ISSN: 1550-7408
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: SYNOPSIS. Temperature strongly influenced morphogenesis of intracellular trypomastigotes in cell culture infected with 2 different strains of T. cruzi. With the Gilmar strain the amastigote-to-trypomastigote differentiation readily occurred at 33 and 37 C, whereas with the CL strain differentiation took place at 33 C but was inhibited at 37 C. The possibility of this selective thermosensitivity resulting from mutational adaptation of the parasite is discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 10208-10215 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 2231-2235 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: High-density amorphous water is studied by neutron scattering in a Q range extending to 16 A(ring)−1. The low density form of amorphous water is also analyzed and compared with previous results. There are very important differences in the composite pair correlation functions of the two forms of amorphous ice, in particular beyond the first nearest-neighbors distance. We conclude that the hydrogen bond network is strongly deformed in a manner analogous to that found in water at high temperature. This is in contrast with the behavior of the pair correlation function of low-density amorphous water, which is closer to that of supercooled water.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 30 (1997), S. 761-764 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Small-angle neutron scattering (SANS) experiments were performed on micellar solutions of octyl-β-glucoside (OBG) in water and on solutions of OBG + glycine in water. A detailed analysis of the results obtained for different concentrations (from 0.026 to 1 M) of glycine and OBG shows that: (i) the structure of the micelles of OBG is always ellipsoidal with the long axis increasing as the concentration of OBG increases from the critical micellar concentration (c.m.c. = 0.022 M) to 1 M; (ii) there is a tendency to form aggregates at concentrations of OBG smaller than 0.5 M; (iii) steric repulsive interactions are clearly seen for concentrations above 0.6 M. The virial coefficient is evaluated as a function of the concentration in OBG. The negative values at low concentration reveal the presence of attractive interactions, while at high concentration the repulsive steric interaction dominates. At high concentration of OBG, the spectra with or without glycine are the same. The analysis shows that glycine remains in water and that its presence does not affect the structure of the micelles.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Physica B: Physics of Condensed Matter 180-181 (1992), S. 762-764 
    ISSN: 0921-4526
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 21 (1988), S. 781-785 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Fractal structures are characterized by self similarity within some spatial range. The mass distribution in a fractal object varies with a power D of the length R, smaller than the dimension d of the space. When the range of physical interest falls below 1000 Å, scattering techniques are the most appropriate way to study fractal structures and determine their fractal dimension D. Small-angle neutron scattering (SANS) is particularly useful when advantage can be taken of isotopic substitution. It is easy to show that the scattering law for a fractal object is given by S(Q), ̃Q−D, where Q is the magnitude of the scattering vector. However, in practice some precautions must be taken because, near the limits of the fractal range, there are important deviations from this simple law. Some relations are derived which can be applied in relatively general situations, such as aggregation and gelation. The effects of polydispersity, important, in particular, in situations described by percolation models, are also shown.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Molecular Structure 250 (1991), S. 213-230 
    ISSN: 0022-2860
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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