ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
[Tetra(2,3-pyrido)porphyrazinato]iron(II) Compounds with Isocyanides as Axial LigandsAliphatic and aromatic monodentate isocyanides RNC (R = t-Bu, c-Hx, substituted Ph) react with [tetra(2,3-pyrido)-porphyrazinato]iron(II) (TPyPFe) to form the corresponding diaxially substituted [tetra(2,3-pyrido)porphyrazinato]iron(II) compounds TPyPFe(RNC)2 1a-8a. The spectroscopic data and thermal properties of the complexes are described and compared with the analogous PcFe(CNR)2 compounds 1b-8b.
Notes:
Aliphatische und aromatische einzähnige Isocyanide RNC (R = t-Bu, c-Hx, substituiertes Ph) reagieren mit [Tetra(2,3-pyrido)-porphyrazinato]eisen(II) (TPyPFe) zu diaxial substituierten [Tetra(2,3-pyrido)porphyrazinato]eisen(II)-Verbindungen TPy-PFe(RNC)2 1a-8a. Die spektroskopischen und thermischen Eigenschaften der Komplexe werden beschrieben und mit denen der analogen PcFe(CNR)2-Verbindungen 1b-8b verglichen.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19881210704
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