ISSN:
0894-3230
Keywords:
allyl alcohol
;
oxidation
;
alkaline periodate
;
palladium(II) catalyst
;
Chemistry
;
Theoretical, Physical and Computational Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The oxidation of allyl alcohol by alkaline species of periodate, H2IO63-, was found to be catalysed by micro amounts of Pd(II) in 0.2 mol dm-3 alkali solution. The active species of the catalyst was found to be PdCl+. A mechanism involving the interaction of the catalyst and substrate in prior equilibria leading to the formation of a π-complex is proposed and the rate is derived. © 1998 John Wiley & Sons, Ltd.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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