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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 62 (1993), S. 231-233 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: (Ba,Ca)TiO3 samples with the ratio of (Ba+Ca) to Ti as unity but prepared by (i) a semiwet route involving (Ba,Ca)CO3 solid solution precursors and TiO2 and (ii) the conventional dry route involving BaCO3, CaCO3, and TiO2 powders, exhibit diffuse and BaTiO3-type sharp ferroelectric phase transitions, respectively. Rietveld analysis of neutron powder diffraction data from the two types of samples shows that, whereas in the samples prepared by the semiwet route, Ca2+ exclusively occupies the Ba2+ site, nearly half of the substituted Ca2+ occupies the Ti4+ site in the case of samples prepared by the dry route. We show that Ca replacement at the Ba site leads to diffuseness whereas Ca introduction at the Ti site leads to sharpening of the transition. To our knowledge, this is the first clear demonstration of the powder synthesis procedure affecting the substitutional sites in multicomponent ceramics and this, in turn, influencing their physical behavior drastically.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 106-108 (1973), S. 1010-1017 
    ISSN: 1420-9136
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The spatial and temporal distribution of total ozone over India and its vertical distribution in theatmosphere during 1964–1969 was studied using Dobson spectrophotometer data at a network of six stations in India, Srinagar (34°N), New Delhi (28°N), Varanasi (24°N), Ahmedabad (23°N), Dum Dum (22°N), and Kodaikanal (10°N). The annual and seasonal variations show a clear phase-shift in the occurrence of the ozone maxima and minima as one proceeds from higher to lower latitudes in the tropics. In the northern stations (north of 25°N) the increase in total ozone during the course of the annual variation is caused by the fractional increase in all layers from the ground to 28 km, the main contribution coming from 10–24 km. Above 28 km the concentration changes roughly in accordance with photochemical production. In lower latitudes (south of 25°N) an increase in total ozone amount during the annual cycle is caused by a gradual increase in all the layers from the ground to 36 km above which the variation is negligible.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 106-108 (1973), S. 1124-1138 
    ISSN: 1420-9136
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Using a modified Brewer bubbler ozone sensor, continuous measurements of the ozone concentration near the ground were made at Poona (18°N, 73°E) for one year 1969–1970. The surface ozone concentration shows a pronounced seasonal variation, with a minimum during the monsoon months and a maximum during the pre-monsoon summer months. There is also a marked diurnal variation in surface ozone concentration which clearly follows the diurnal variation of temperature and is again a maximum during the summer months and a minimum during the monsoon. A secondary maximum in ozone concentration occurs in the forenoon during the winter months, associated with the temperature inversions that occur near the ground in this season. Both ozone and radioactive tracers, such as Cs-137 both in air and in precipitation show variations indicating that they have identical source regions and sinks. The latitudinal anomaly of surface ozone and Cs-137 observed in the low latitudes over India is explained as arising from the reduction in the rate of transfer of these tracers from the stratosphere to the troposphere, as a result of the reversed circulation at the upper levels in this season. From continuous measurements of surface ozone made with three electrochemical sensors exposed at three levels, 0, 15 and 35 m above the ground, the ozone flux has been directly calculated for the first time in the tropics. The ozone flux was calculated using both the rate of decay method used by Kroening and Ney and Regener's profile method. The profile method gives values of the order of 1.71 to 7.04×1011 mol/cm2/sec and that obtained by the rate of decay method is found to be 4.2 to 5.6×1011 mol/cm2/sec and are in good agreement with the flux values reported by other investigators.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 106-108 (1973), S. 1097-1105 
    ISSN: 1420-9136
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Short-term fluctuations superimposed on the diurnal variations of surface ozone recorded at Poona during 1969–1970 are discussed. While there is a net production of ozone during electrical discharges in a thunder cloud, the surface ozone recorder often registered a decrease in surface ozone concentration. This decrease coincided with updraughts generated during the formation of a thunderstorm. Similar sharp increases in ozone were observed with downdraughts. In cases of lightning without the development of a thunderstorm over the station, an increase in ozone density was observed just after the first lightning discharge. Apart from the fluctuations associated with thunderstorms in summer, sharp fluctuations in density were also noticed during winter, in the mornings. Abrupt falls in ozone occur with the formation of a stable layer near the ground at night and a sudden surge after the breaking up of the layers in the morning. The changes in ozone are, however, much more pronounced than those in temperature and wind and this striking correlation between surface ozone, surface air temperature and wind provides a unique tool for the study of low-level temperature inversions, their establishment and destruction.
    Type of Medium: Electronic Resource
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