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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inorganic and organometallic polymers and materials 10 (2000), S. 265-272 
    ISSN: 1572-8870
    Keywords: functionalized polymethacrylates ; organoiron polymers ; cationic cyclopentadienyliron complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A novel approach to the synthesis of polymethacrylates containing cationic cyclopentadienyliron moieties pendent to their side chains was accomplished via the use of π-coordinated organoiron complexes. The complexed methacrylates were polymerized in the presence of AIBN to give soluble organoiron polymethacrylates (6a and 6b, 10, 14a and 14b) in 80–90% yields. Photolytic demetallation of the organoiron polymers allowed for the isolation of their organic analogues (7a and 7b, 11, 15a and 15b) whose weight average molecular weights ranged from 48,500 to 68,300.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inorganic and organometallic polymers and materials 8 (1998), S. 127-133 
    ISSN: 1572-8870
    Keywords: Soluble organoiron polymers ; polyethers ; polythioethers ; nucleophilic substitution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Synthesis of novel organoiron polymers containing oxygen, sulfur, and/or nitrogen bridges was achieved via nucleophilic aromatic substitution polymerization of cyclopentadienyliron complexes of chloroarenes with a number of aliphatic and aromatic dinucleophiles.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inorganic and organometallic polymers and materials 10 (2000), S. 189-208 
    ISSN: 1572-8870
    Keywords: polyaromatic ethers ; pentamethylcyclopentadienylruthenium ; cyclopentadienyliron ; heterometallic polymers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A variety of homometallic (Cp*Ru+) and heterometallic (CpFe+–Cp*Ru+) oligomers with one to five metal moieties were prepared in high yields (74–90%) via nucleophilic aromatic substitution reactions. For the mixed metal systems, it is shown that the arrangement of the metal moieties along the backbone can be controlled. In addition, the synthesis of heterometallic polymers is described, along with their decomplexation and thermal properties. It was found that the thermal properties and solubility of the systems are greatly dependent on the linkages within the polymer backbone.
    Type of Medium: Electronic Resource
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