ISSN:
0009-2940
Keywords:
Octabisvalene, 3-, 2,3-, and (Z)-3,7-(di)functionalized derivatives
;
NMR Analysis, 13C,13C coupling constants
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Functionalized OctabisvalenesQuadricyclanone (13) is the starting material for a five-step synthesis of 3-cyanooctabisvalene (24, 19% total yield), cyclooctatetraene for a six-step synthesis of (Z)-3,7-dicyanooctabisvalene (58, 7% total yield). By decyanation of 24, the parent octabisvalene (1) is produced. NMR data, including 13C,13C coupling constants, are presented.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240814
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