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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We describe the results of the transmission electron microscope study of ordered and modulated structures in InGaP alloy semiconductors grown on (001) GaAs substrates by metalorganic vapor phase epitaxy, chloride-vapor phase epitaxy, and liquid phase epitaxy. Strong ordering of CuPt-type has been observed in InGaP grown by metalorganic vapor phase epitaxy at 630 °C, which is associated with an abnormality in the photoluminescence peak energy. CuPt-type ordered structures have also been observed in crystals grown by chloride-vapor phase epitaxy, but the degree of ordering is weaker and crystals grown at 576–740 °C exhibit normal photoluminescence peak energies. On the other hand, in crystals grown by liquid phase epitaxy, no ordered structure is found and the crystals exhibit normal photoluminescence peak energies. There is no dependence of modulated structures on the growth method since they are observed in all crystals. These results also lead us the previous conclusion by Kondow and co-workers that the ordered structures are not generated under thermal equilibrium conditions but rather by the diffusion and reconstruction of deposited atoms on the growth surface.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 2755-2757 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: CdTe-ZnTe strained-layer superlattices (SLSs) were grown on GaAs by hot-wall epitaxy. The individual layer thickness of the SLS is well controlled and the thickness fluctuation is less than ±1 monolayer. High-resolution transmission electron microscopy images show coherent SLS growth. We found that two-thirds of the threading dislocations can be reduced by inserting the SLS in CdTe/GaAs.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 445-447 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The nature and behavior of antiphase boundaries in GaAs/Si heterostructures using GaP, GaP/GaAsP, and GaAsP/GaAs strained-layer superlattices as intermediate layers have been studied by transmission electron microscopy. The antiphase domains are found to be very complicated three-dimensional polygons consisting of several subboundaries in different orientations. Self-annihilation of antiphase domains during crystal growth of GaAs on (001) 0.4° off or (001) 2° off Si substrates is directly observed for the first time through plan-view and cross-sectional observations. Based on these findings, a mechanism of annihilation of these domains is presented.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 2312-2314 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: InGaP crystals grown on (110) GaAs substrates by chemical vapor deposition have been structurally investigated by transmission electron microscopy. No superstructure spots are present in electron diffraction patterns from (110) plan view and (11¯0) and (001) cross sections. However, composition-modulated structures with strong amplitude are found not only in the 〈001〉 but in the 〈11¯0〉 directions. They are found to be stable in the form of columnar domains during crystal growth. These results strongly suggest that atomic ordering and spinodal decomposition of the crystal are competing on the growth surface via surface diffusion of deposited atoms.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 622-626 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Intrinsic gettering centers in oxygen-free silicon crystals after a high–low–medium-temperature annealing cycle were successfully identified using transmission electron microscopy and energy dispersive x-ray spectroscopy. These centers have a butterfly-type shape and they consist of interstitial-type extended multiple dislocation loops in {110} planes of 0.1–0.7 μm diameter and a high density of small 3–15-nm-diam precipitates located inside the dislocation loops and/or on the dislocation line. Compositional x-ray analysis identified Cu as the predominant metal component of the precipitates. Occasionally Ni and very rarely Fe were also detected.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 2587-2587 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 359-364 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The dislocation density in bulk GaAs crystals (up to 4 mm thick) grown by liquid-phase electroepitaxy (LPEE) is found to be significantly reduced (by as much as a factor of 20) relative to that in the substrate. This reduction takes place when the thickness of the growing crystal exceeds a critical value of 50–70 μm. It is accompanied by a formation of misfit dislocation arrays identified by transmission electron microscopy in the interface region between the substrate and grown crystals. These findings suggest that the reduction of the dislocation density is caused by a small but finite lattice mismatch between the growing epitaxial-quality crystal and the relatively inferior quality melt-grown substrate. Dislocations which propagate from the substrate into the LPEE crystal are forced by the misfit stress to move laterally forming misfit dislocations.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 615-621 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new intrinsic gettering process was found in silicon crystals subjected to a three-step annealing sequence. The process involves native point defects (silicon interstitials) rather than residual oxygen impurity, and thus it can be realized in crystals with low or virtually zero oxygen concentration. The key characteristics of the process (i.e., denuding and gettering efficiency and the role of annealing ambient) are discussed in conjunction with a kinetic model involving diffusion of silicon interstitials. The identity of the intrinsic gettering centers was pursued by transmission electron microscopy.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 58 (1985), S. 2448-2452 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We fabricated and life-tested visible AlGaAs/GaAs channeled-substrate-planar-type lasers and found that some are degraded within 100 h of operation. We investigated these using photoluminescence and transmission electron microscopic images. The characteristic features in photoluminescence images are dark defects that run parallel to the channeled stripe. Using transmission electron microscopy, we found that these dark defects are composed of precipitates, dislocation loops, and dislocation dipoles. In order to know the relation between these degradation phenomena and the thermal strain induced by lattice mismatch, we calculated the stress distribution in the semiconductor laser using the finite element method. According to this simulation, a stress concentration in the active layer arises near the edges of the channeled stripe where the volume dilatation is maximal. Combining the results of experiments and simulation, we concluded that interstitial atoms created by nonradiative recombination migrate to the edges of the stripe, and that ultimately dark defects appear near the edges of the stripe.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 2194-2196 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Lateral patterning of arsenic precipitates in GaAs is reported. The positions of near-surface precipitates in a GaAs layer grown by molecular beam epitaxy at low temperature are controlled by InGaAs stressors 45 nm in width covered by a SiO2 film. The stressors form a surface grating which governs the precipitate position by modulating the strain in the GaAs near the surface. Electron microscopy clearly reveals the formation of precipitates about 15 nm in diameter aligned with the stressors at a depth of ∼50 nm. It is suggested that this capability to control the position of nanometer-size metallic particles within a semiconductor could open up new possibilities for novel devices. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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