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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 17 (1984), S. 1208-1219 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 1209-1220 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polyimide block copolymers with diacetylene functionality were prepared in a two-step process: (1) oligomeric imide formation terminated with 1-amino-3-ethynylbenzene, and (2) oxidative coupling of the acetylene-terminated polyimides with p- and/or m-diethynylbenzene or bispropargyl ether of Bisphenol A to form block copolymers, or oxidative coupling within themselves in the presence of a copper (I) catalyst. The resulting copolymers were crosslinked with UV irradiation or thermal treatment. The thermal crosslinking process and the thermal stability of the crosslinked materials were studied by differential scanning calorimetry (DSC) and isothermal gravimetric analysis (IGA), respectively.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 2119-2147 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The effects of chain structure and processing variables on the microstructure and linear viscoelastic behavior of a series of copolyether-ester block polymers are described. In addition, the random copolyester analogs of the hard block are examined. The ester segments are composed of two isomers, poly(tetramethylene terephthalate) (PTMT) and poly(tetramethylene isophthalate) (PTMI), which possess significantly different crystallization kinetics. The ratio of PTMT to PTMI in the series has been systematically varied to alter the crystallizability without changing the chemical composition. The results of differential scanning calorimetry, wide-angle x-ray diffraction, and dynamic mechanical characterization are presented. Copolymerization of a second ester shortens the average sequence length of the first ester, resulting in melting-point depression for crystals of the first polyester and substantial lowering of the dynamic mechanical storage modulus above the glass transition of the intercrystalline phase. The melting-point depression may be predicted by using Flory's model for random copolymers, but the calculated heats of fusion are significantly lower than those obtained from diluent melting-point depression.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 8 (1987), S. 237-243 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Measurements of dynamic viscoelastic in-plane shear modulus have been made for unidirectional carbon fiber composites with amorphous engineering thermoplastics as the binder resins. The viscoelastic response is modeled by a three-phase, finite-element model in which fiber placement in the plane perpendicular to the fiber axes is largely disordered. In the model, fibers tend to chain with the distance of closest approach dictated by several factors, including the tendency for the resin to wet the entire fiber surface. Polished section microscopy supports the assumed microstructure. The model includes an adsorbed primer layer at the fiber interface with perturbed viscoelastic response. The model is useful throughout the temperature range up to and including the glass transition of the binder resin.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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