ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction mechanism of controlled hydrolysis of the inorganic ring system (NPCl2)2NSOCl in the presence of KCl and 18-crown-6 has been revised and is explained from steric constraints rather than from electronic considerations. The X-ray structure of one of the hydrolysis products, [KC12H24O6]+-[NHPO2NPCl2NSOCl]-, shows a dimeric structure of two centrosymmetrically related formula units kept together by hydrogen bridges and K … O coordination. Crystals are monoclinic, space group C2/c with a = 25.698(5), b = 8.223(2), c = 23.665(4) Å, β = 106.03(1)°, V = 4806(2) Å3, and Z = 8. The final R and Rw values are 0.048 and 0.044, respectively.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520050405
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