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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 104 (1996), S. 6369-6374 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Recently, it has been pointed out that the structure of shear ordered colloidal dispersions can adequately be accounted for by the intensity distribution I(l) along Bragg rods [Phys. Rev. Lett. 75, 763 (1995)]. Information concerning packing of the shear induced layers and on their stacking order is contained in I(l). In this paper I(l) is determined by measuring the small angle neutron scattering distribution as a function of the sample orientation. For the investigated charge stabilized system with particle diameter σ=143 nm and a distance of nearest neighbors in the layers a=237 nm, a structure close to random close-packed hexagonal layers is found. As compared with close-packed systems the distance between the layers c is elongated so that c≈a. Further, it is shown that the application of shear leads to a more uniform distribution of I(l) along the rods, which demonstrates that the loss of correlation between the hexagonal layers under sheared conditions can also be determined by small angle neutron scattering. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 10 (1994), S. 1351-1353 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 10 (1994), S. 3043-3045 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 1283-1289 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Dynamic light scattering experiments are reported on crystal-like ordered colloidal suspensions composed of two types of electrostatically interacting particles having similar size and effective particle charge. The particles differ only in their refractive indices. We obtain the incoherent (self) intermediate scattering function of these mixtures by using only a trace concentration of one of the species and matching the refractive index of the suspending liquid medium to that of the other. Localization of the tracer particles about randomly located lattice sites of the colloidal crystal is manifested in the nonergodicity of the incoherent intermediate scattering functions. The latter, and the particle mean-squared displacements obtained from them, plateau to finite values at long times. In analogy to neutron scattering these plateau values of the incoherent intermediate scattering functions may be called the elastic incoherent structure factor. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 116 (2002), S. 2658-2662 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Although rheology as well as neutron and x-ray scattering studies of ordered dispersions have been performed no coherent picture is discussable. In this paper we report our synchrotron x-ray and neutron scattering data of concentrated, charge stabilized, monodisperse polymer colloids and compare them with rheological data. We found that the scattering data can be understood in terms of viscoelastic flow. When ordered by flow-, solid- and liquid-like behavior can be separated with two independent experiments: (a) The solid-like character can be seen at perpendicular incidence as Bragg reflections, (b) the liquid-like character becomes apparent by sample rotation as the intensity distribution along Bragg rods. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 210-211 
    ISSN: 0009-286X
    Keywords: Hochdruck ; Messung ; Volumen ; Druck ; Temperatur ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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