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  • 1
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 56 (1991), S. 2270-2272 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 62 (1991), S. 1311-1316 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The article outlines the hardware and software components of a general-purpose, PC-based temperature programming system. The multichannel thermocouple readout unit can switch, under computer control, among several modes of operation: calibration, analog cold junction compensation, differential temperature reading. The heating power is proportional to the output of a 12-bit DAC and is delivered by an efficient switching power supply. On the software side, we first introduce the development environment and the algorithms used to compute the control action. We show that an adaptive strategy outperforms the traditional proportional-integral-differential approach, and yields fast and accurate temperature responses when driving devices with widely different thermal characteristics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 65 (1994), S. 1897-1902 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The relationships between signal processing schemes and expected performances of several types of NMR transceiver are discussed to show how emerging digital technologies may be used in future systems. We identify a transceiver architecture where accuracy of the analog signal processing functions is not critical, and top performances are obtained through real-time digital signal processing. Our receiver, comprising an oversampling analog-to-digital converter scheme, achieves a dynamic range of 12 bits at bandwidths above 1 MHz, and a dynamic range in excess of 16 bits at bandwidths 〈15 kHz. We give an outline of specifications and hardware design issues of the main parts of this transceiver and demonstrate experimentally the superior performances of our receiver.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 67 (1996), S. 2123-2129 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We illustrate the principles of digital quadrature detection and call attention to its various benefits (ghost-free spectra and high immunity to low-frequency interference) and its intrinsic capability of generating data sets with different aliasing behaviors. A function describing the filtering efficiency is introduced, and the digital filters of our detector are compared with their analog counterparts of conventional nuclear magnetic resonance spectrometers. With an appropriate analog-to-digital converter (ADC), our digital detector has a dynamic range which is essentially limited by the analog noise, and increases when the spectral bandwidth is reduced. These nearly ideal performances are achieved through dithering, which randomizes the quantization error and oversampling, which reduces the quantization noise in the band of interest. We introduce a "figure of merit'' for AD converters which estimates the noise performances of ADCs, and allows to compare products which achieve different compromises between speed and accuracy. The distortions due to the nonlinearities of the ADCs are analyzed through simulations. We find that the majority of the spurious signals (i.e., the errors other than noise) occur outside the band of interest, and are disposed through digital filtering. An unexpected result of the simulation is that, in some circumstances (e.g., large-scale narrowband dithering), an increase in the number of bits of the ADC may actually reduce the distortion-free dynamic range. In Sec. VIII we analyze practical problems like the role of the aperture jitter and the selection of the sampling frequency. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 57 (1986), S. 1349-1353 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A NMR programmer is described which is built around a logic idea and a set of specifications, rather than availability of special or new integrated circuits. We begin by discussing what a quintessential Touring machine can do to solve the problem of outputting words (or pulses) with the resolution of the system clock over arbitrarily long time intervals. We then illustrate a simple realization of this machine, with 4096 program lines, 25-ns resolution, two 16-bit output lines, the possibility of nesting loops down to the 256th level, and a component cost in the 102 $ range. A software "human'' interface has been developed in an IBM-PC compatible (MS-DOS) environment, which simplifies the task of debugging the entire NMR spectrometer, and that of designing new experiments. While certainly overspecified for all traditional solid-state NMR experiments, our programmer may meet the requirements of recently suggested selective excitation and imaging experiments in liquids.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 7532-7540 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The thermodynamics of hydration of biomolecules is experimentally studied in the β-cyclodextrin (β-CD), which contains water molecules in a range of configurations and has been proposed as a model system for complex biomolecules. The thermal measurements point to the role of a structural transition from the hydrated β-CD (phase I) to a "dehydrated'' form (phase II). We show that dehydration in phase I is assisted by a "compensation mechanism'' for which β-CD contributes a constant amount of energy for each H2O mole. Despite the presence of different types of H2O's, water losses in phase I are accurately described in terms of this energy and the isosteric molar enthalpy of dehydration. Moreover, in going from the fully hydrated to the fully dehydrated form, the contribution of β-CD to dehydration is over all equal to the enthalpy of transition from phase I to phase II. Our analysis yields the changes of an enthalpy associated with the biomolecule alone as a function of the water content. In the case of β-CD, we can sketch a qualitative phase diagram, which assists the interpretation of details of our thermal experiments. The role of kinetic factors in the attainment of the thermodynamic equilibrium is investigated with 2H-NMR in samples recrystallized from heavy water. We find that, over a wide range of hydration levels, water molecules have a liquidlike diffusion, which, together with the compensation mechanism, explains the fast and nearly reversible dehydration of the β-CD. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 114 (1992), S. 9836-9845 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2392-2400 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An analysis of the 109Ag isotropic chemical shift δ in the glasses of the AgI:Ag2O:B2O3 system is presented. In these glasses, δ covers a range of ∼500 ppm but does not depend linearly upon the fraction of I− anions X=[I]/[Ag]. This means that, when AgI is added to the borate network, structures are preferentially formed in which silver is coordinated to both I− and negatively charged borate groups. We discuss also the 109Ag chemical shift range covered by the different forms of AgI and the dependence of δ upon the BO4 units and non-bridging-oxygen (NBO's) concentrations. We analyze the relationship between spatial compositional fluctuations and NMR–MAS width of the 109Ag line in fast silver conducting glasses. The spin-lattice relaxation of 109Ag and 11B, as well as some of the 109Ag line narrowing results, are quantitatively interpreted by assuming a distribution of Ag+ jump times and by discussing how the different nuclear interactions are affected by the diffusion of silver. We conclude that the NMR evidence does not support the microscopic picture of cation diffusion in vitreous electrolytes suggested by the weak electrolyte theory.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1862-0760
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Two composite gel electrolytes prepared from mixtures of poly(acrylonitrile) (PAN), propylene carbonate (PC), ethylene carbonate (EC) and LiClO4 have been studied with differential scanning calorimetry (DSC) and7Li-6Li NMR. The data allow estimation of ionic conductivities, local (short range) diffusivities, and lattice dynamics. Furthermore, they point to an unexpected behavior of the Li-rich sample that hints to a complex LiClO4-PAN phase diagram.
    Type of Medium: Electronic Resource
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