ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A regioselective cyclohexannulation procedure, whose key step involves the [4 + 2] cycloaddition of dienamines 12-24 with methyl acrylate, allows the conversion of cycloalkanones 1-11 to bicyclic dienoates 25 - 37. The chemistry of 26 is briefly examined and, in the context of organoleptic studies concerning functionalised 5,5,9-tri-methyldecalins, the transformation of 37 to ketones 44 and 46 as well as to acetates 53-56 is described.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19890720505
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