ISSN:
1434-1948
Keywords:
Germanium
;
Nitrogen
;
Silicon
;
Titanium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of dippNSiMe3Si(NH2)3 (1) (dipp = 2,6-iPr2C6H3) with Cp*TiMe3 (Cp* = C5Me5) and Me3SnCl yields the new heterocyclic adamantane (dippNSiMe3Si)2(Cp*Ti)2(NH)6 (2) containing the Si2Ti2(NH)6 core and the silicon-nitrogen six-membered ring compound [dippNSiMe3Si(NH2)NH]3 (4). [dippNSiMe3Ge(NH2)2]2NH (5) reacts with AlMe3 to give the germanium-nitrogen six-membered ring compound [dippNSiMe3Ge(NH2)NH]3 (6). The compounds 2, 4 and 6 have been structurally characterized by single-crystal X-ray structural analysis.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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