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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 4569-4576 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 628-638 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A molecular dynamics study of the friction experienced by the dye molecule resorufamine rotating in a polar solvent is performed. The validity of simple continuum theories of dielectric friction is tested. It is found that the Alavi–Waldeck theory gives reasonable results for the zero frequency dielectric friction coefficient while the Nee–Zwanzig theory requires an unphysically small cavity radius. A procedure for evaluating the time dependent friction kernel from torques and angular velocities, which enables the contributions to the friction from the van der Waals and Coulomb forces to be evaluated separately, is suggested. This study of a realistic system shows that electrostatic interactions can enhance friction by at least two physical mechanisms. First is a contribution to the friction which arises solely from retardation of the solvent reaction field. Second is a contribution arising from local structural changes of the solvent which are driven by the electrostatic field, i.e., a change in the local viscosity. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 11 (1995), S. 1849-1851 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 63 (1992), S. 2913-2921 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The characteristics of various cw mode-locked dye lasers were thoroughly explored, and the characteristics of a pump/probe apparatus employing two such lasers pumped by a single mode-locked pump laser. First, it was observed that the rf source used to drive the acousto-optic mode-locking element in the pump laser, while not affecting the average power or obtainable pulse width, had a profound effect on the noise characteristics of the pump laser, which are in turn passed along to the dye lasers. For a driver based on a tunable frequency synthesizer, pulse jitter on the order of 300 ps was observed, which represents ≈2.5% of the total interpulse time interval. This was deemed unacceptably high, and use of this mode-locker driver was discontinued. For a driver with a fixed frequency reference source (an oscillating quartz crystal), pulse jitter on the order of 5 ps was measured, a great improvement over the other driver. Next we studied various dye laser configurations pumped by this pump laser. We found that for time resolution of several picoseconds, a pair of synchronously pumped dye lasers employing birefringent filter tuning elements was an excellent source of independently tunable pulse trains, and that these pulse trains were well synchronized with each other despite the absolute timing jitter in the pump pulse train. To obtain better temporal resolution with independently tunable lasers was more problematic, however. A hybridly mode-locked laser (employing a saturable absorber within a synchronously pumped dye laser) can produce shorter pulses (≤100 fs has been reported), but the lack of temporal synchronization between two of these lasers limits the resolution of a two wavelength experiment to several picoseconds. An attempt was made to reduce this relative timing jitter by crossing two independently tunable hybrid lasers through a common intracavity saturable absorber, thereby temporally locking the pulse trains together. This mechanism failed to work well on time scales longer than a millisecond.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 6540-6549 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The fluorescence decays from submonolayers of pyrene separated from Si(111) by Xe spacer layers are measured as a function of spacer thickness (17–200 A(ring)), pyrene coverage, and emission wavelength. The results are explained in terms of two decay channels: energy transfer and trapping among the molecules in the two-dimensional pyrene overlayer, and excitation of electrons from the valence to the conduction band in the Si(111) by the dipole near field of the electronically excited pyrene molecule. The intralayer energy transfer is modeled using the Kohlrausch equation N(t)=N0 exp(−t/τ)α, in which α is related to the distribution of pyrene molecules in energy. Energy transfer from the molecule to the semiconductor is modeled using the classical image dipole theory. The classical model is used to calculate the energy transfer rates from a dipole to Si and GaAs as a function of dipole–semiconductor separation, and as a function of dipole emission wavelength.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 3580-3581 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 4055-4066 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Polarization spectroscopy has been developed as a useful method for the investigation of molecular reorientation in both liquid phase solutions and in the gas phase. This technique has the advantage of measuring a single particle orientational correlation function directly but the disadvantage of averaging over rotation in all electronic states. Described and characterized herein is a variant of this technique, optically heterodyned polarization spectroscopy, which is able to disentangle various contributions to the signal and determine the rotational relaxation of the solute molecule in different electronic states independently. This work also demonstrates the measurement of the normalized value of the orientational correlation function at time zero, r(0), without extensive normalization of laser parameters. Lastly, various technical advantages of the optically heterodyned method are discussed.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 6770-6783 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rotational diffusion of three mechanically similar phenoxazine dyes possessing distinct electrical properties was studied in isopropanol. The results, along with previously presented results from other polar solvents, were analyzed in terms of continuum theories for rotational dielectric friction. It was found that a continuum based theory can account for the observed rotational relaxation dynamics, but only with realistic modeling of the solute charge distribution (not a point dipole), and by accounting for both frequency and wave vector dependences of the solvent dielectric properties.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 943-952 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Studies of the photoisomerization of 4,4'-dimethylstilbene in n-alkane solvents are reported. As with similar studies it is possible to identify an activation barrier to isomerization and the viscosity dependence of the isomerization is not adequately explained by a one-dimensional hydrodynamic Kramers equation. Comparison of the isomerization rates with those of other stilbenes suggests that the use of a frequency dependent friction for the solvent does not consistently explain the data. These results and those of other stilbenes can be explained by a two-dimensional isomerization coordinate where the reaction trajectory is linked to the solvent viscosity.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 2305-2316 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: New data for the photoisomerization dynamics of t-stilbene and 4,4'-dimethoxystilbene in polar solvents are reported. These data demonstrate that in n-alkyl nitriles, nonassociated polar solvents, it is possible to extract a solvated barrier for the isomerization. This result is contrasted with recent studies in n-alkyl alcohols, associated polar solvents, where this separation is not possible and clarifies the origin of the changing barrier height in n-alkyl alcohols. Comparison of reduced isomerization rates with models of chemical reaction dynamics in solution are drawn. Good agreement of the data with a coupled oscillator model is found.
    Type of Medium: Electronic Resource
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