Library

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Direct mapping of vibrational-specific angular distributions of the polyatomic reaction product: CN+D2→DCN+D (1996)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 3332-3335 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A newly developed Doppler-selected time-of-flight (a 3D) method was applied to map out for the first time the vibrational-specific angular distributions of the DCN product from the title reaction. A tentative vibrational assignment was given for the observed structures. It was found that the nascent DCN is formed with substantial excitations in both C–D stretch and DCN bend modes. While the pure C–D stretch and those associated with low bend excitations are predominantly backward scattered, the highly excited DCN in both modes also exhibit a substantial forward scattered component in the angular distribution. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.472187
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Experimental and theoretical angular and translational energy distributions for the reaction CN+D2→DCN+D (1997)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 7869-7875 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This paper presents new measurements of angular and translational energy distributions for the title reaction at a reagent kinetic energy of 5.8 kcal/mol, and compares them with the corresponding results from quasiclassical trajectory calculations based on an accurate global potential energy surface. The comparison of theory and experiment is generally good; however, the minor deviations that we find provide valuable information concerning errors in the potential energy surface. Both experiment and theory indicate that CN+D2 is a simple abstraction reaction, with predominantly backward-scattered angular distributions and about 37% of the available energy ending up in product translation. Strong dependence of the calculated angular and translational energy distributions on reagent kinetic energy is noted. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.475099
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Reaction dynamics of O(1D)+H2, D2, and HD: Direct evidence for the elusive abstraction pathway and the estimation of its branching (1997)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 2351-2356 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The dependencies of the integral cross sections for the title reactions on collision energies were determined from 0.6 kcal/mol to nearly 6 kcal/mol. The result provides, for the first time, direct and unambiguous experimental evidence for the existence of an abstraction pathway, in addition to the widely accepted inserted one. A reaction barrier of about 1.8 kcal/mol was found for this elusive abstraction channel. The branching of these two microscopic pathways was estimated. An intriguing H/D isotope effect was revealed, which called for further studies. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.474579
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...