ISSN:
1013-9826
Source:
Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
This paper describes a new method for prediction of the Chapman–Jouguet detonationparameters of CaHbNcOdLieMnf explosives for mixture of some of low temperature explosionexplosives at [removed info]0 = 1000 kg/m3. Explosion temperatures of water-gel explosives and explosiveformulations are predicted using thermochemistry information. The methodology assumes that theheat of detonation of an explosive compound of products compositionH2O–CO2–CO–Li2O–MnO2–Mn2O3 can be approximated as the difference between the heats offormation of the detonation products and that of the explosive, divided by the formula weight of theexplosive. For the calculations in which the first set of decomposition products is assumed,predicted temperatures of explosion of water-gel explosives with the product H2O in the gas phasehave a deviation of 153.29 K from results with the product H2O in the liquid state. Lithium andmanganese oxides have been prepared by the explosion of water-gel explosives of the metal nitrates,M (NO3) x (M = Li, Mn) as oxidizers and glycol as fuels, at relative low temperature. We have alsoused the Dulong-Petit’s values of the specific heat for liquid phase H2O. Lithium manganese oxidepowders with chrysanthemum-like morphology secondary particles, but with smaller primaryparticles of diameters from 5 to 30 nm and a variety of morphologies were found. The oxidesproduced by this cheap method affirmed the validity of explosion synthesis of nano-size materialsfor lithium ion batteries
Type of Medium:
Electronic Resource
URL:
http://www.tib-hannover.de/fulltexts/2011/0528/01/52/transtech_doi~10.4028%252Fwww.scientific.net%252FKEM.324-325.193.pdf
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