ISSN:
1022-1336
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The hydrated electron (e-aq) and hydroxyl radical rate constants with 18 acrylate-, methacrylate-, crotonate-, fumarate- and maleate esters are discussed. The constants approach the diffusion-controlled limit. k(e-aq) and k(OH) change in opposite direction; if k(e-aq) is high then k(OH) is small. This tendency is connected with the nucleophilic character of e-aq and the electrophilic character of OH, although the site of attack of e-aq and OH is different: carbonyl versus vinyl group.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/marc.1996.030170511
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