ISSN:
1434-1948
Keywords:
Adamantane
;
Liquid ammonia
;
Oxygen
;
Sulfur and selenium
;
Tin
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of trisSnBr3 (1) [tris = (Me3Si)3C] and nBuSnCl3 with Na2X (X = O, S, Se) yield the heterocyclic adamantanes 2-6. The reaction of 1 with Na2O is carried out in liquid ammonia under normal pressure at -78 °C to give (trisSn)4O6 (2). However, the reaction of 1 with Na2S and Na2Se under pressure at room temperature results in the formation of (trisSn)4S6 (3) and (trisSn)4Se6 (4). nBuSnCl3 reacts with Na2S and Na2Se in liquid ammonia at -33 °C under normal pressure to give (nBuSn)4S6 (5) and (nBuSn)4Se6 (6), respectively.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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