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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of chemical & engineering data 17 (1972), S. 129-133 
    ISSN: 1520-5134
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 59 (1967), S. 48-62 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 240-246 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The isothermal effects of pressure and composition on the mixture and partial enthalpy differences of the methane-propane binary were derived from PVTy data. A graphical and numerical technique was used to derive the enthalpy differences from 100° to 460°F. and 200 to 2,000 lb./sq. in. abs. for the complete composition range of the binary.The isothermal effects of pressure and composition on the mixture enthalpy data of the methane-propane binary were also calculated with the Benedict-Webb-Rubin and the Redlich-Kwong equations of state. The results of the three methods of calculation are compared. The comparison showed that the two-constant Redlich-Kwong equation of state is as good as the eight-constant Benedict equation of state in the superheated vapor region.The data derived in this work were combined with other methane binary enthalpy data from the literature to construct a general correlation of the effect of pressure and composition on the enthalpy of methane-light hydrocarbon binaries. The correlating parameters are the pseudo reduced temperature and pressure and a mole-average acentric factor.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 116-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enthalpies of components in ideal gas mixtures can be computed from existing data. However the isothermal effects of pressure and composition on partial enthalpies of mixture components have not been completely characterized. An investigation of the application of the Redlich-Kwong equation of state to the calculation of partial enthalpies is reported here. Methods are developed for convenient hand calculations and for computations on the IBM-650.Calculated partial enthalpies are compared with values derived from experimental P-V-T-C data for binary hydrocarbon mixtures. The calculated values agree fairly well with the derived data for pressures up to 2,500 lb./sq. in. abs. Best agreement is generally obtained when the mixture is well above the critical temperature of the more abundant component. No consistent bias was indicated however.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 492-497 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An isothermal throttling calorimeter system has been built for obtaining the effects of pressure on the enthalpy of liquids and vapors. The propane-benzene system has been studied at 200°0, 300°, and 400°F. for pressures from 200 to 1,000 Ib./sq.in.abs.The experimental results are evaluated with respect to errors, and the data on the pure components are compared with values from the literature. Calculation methods are employed, and the calculated results are compared with the experimental data in an effort to evaluate the calculation methods.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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