ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract As a result of methylation and subsequent catalytic debenzylation, 1-benzylimidazo[4,5-e][1,4]diazepine was converted to the corresponding imidazo[5,4-e][1,4]diazepine. Thermodynamic parameters of inversion in isomeric imidazo[4,5-e]- and imidazo[5,4-e][1,4]diazepines were determined by dynamic 1HNMR. The total energy of the compounds being compared was calculated by molecular-mechanics methods.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00529379
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