ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A study has been made of the asymmetric hydrosilylation of acetophenone by diphenylsilane under the influence of rhodium complexes with chiral phosphites. The enantioselective nature of the reaction depends on the phosphite structure, the acetophenone/rhodium and ligana/rhodium ratios, and the temperature. The maximum optical yield (24%) is attainod on the complex [Rh(COD)Cl]2/(S, S)-2-ethoxy-4,5-dicarbisopropoxy-1,3-2-dioxophiospholane.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00961341
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