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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 467-471 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Si* Rydberg atoms in plasmas originating from laser ablation of Si were identified, employing deflection plates for electric-field ionization and a quadrupole mass spectrometer. The angle-resolved time-of-flight and yield distributions of these species showed that both the most probable time-of-flight and the yield of the Si* atoms decreased with an increasing detection angle, as in the case of laser ablated neutrals. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 1871-1883 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Laser ablation deposition was used to grow polycrystalline Cu-Ni and Ag-Ni thin films on amorphous substrates at room temperature. X-ray diffraction was employed to determine the phases present and the residual macrostress and to analyze the structural imperfection in terms of crystallite size and microstrain. For confirmation and complementary microstructural data transmission electron microscopy was applied. Analysis of the gross composition was achieved by electron probe microanalysis and x-ray fluorescence. The films contained substantially less Cu and Ag than the targets, which was caused by preferential scattering of ablated Cu and Ag species upon incidence at the growing films. The Cu-Ni films were entirely composed of a CuxNi1−x solid solution. The Ag-Ni films were composed of a AgxNi1−x solid solution and of pure Ag and pure Ni. The nonequilibrium AgxNi1−x solid solution could contain up to 44 at. % Ag. The residual macrostress in the Cu-Ni films was compressive, whereas it was tensile in the Ag-Ni films. The occurrence of these stresses could be interpreted as due to the combined effects of atomic peening and cooling after deposition and, in the case of the Ag-Ni films, of stress relaxation by partial decomposition of the AgxNi1−x solid solution during film growth. The microstrains in the AgxNi1−x solid solutions were higher than in similarly prepared pure elemental Ag and Ni films. Compositional inhomogeneity of the AgxNi1−x solid solution crystallites contributed in particular to this effect. The strain-free lattice parameters of the solid solutions were found to be in fair agreement with those predicted by Vegard's law.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 8055-8064 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Angle-resolved time-of-flight distributions of Si+ ions and of O+, Cu+, and Nd+ ions originating from laser ablation of Si and Nd1.85Ce0.15CuO4, respectively, were measured using a quadrupole mass spectrometer. From these distributions angle-resolved yield distributions of the ions were obtained. The time-of-flight distributions did not change with the detection angle; consequently, neither did the associated yields. The degrees of ionization of the laser-induced plasmas appeared to be about 5×10−7. However, it is argued that only a fraction of the order of 5×10−4 of the total number of ions could have been detected and that thus the actual degrees of ionization were of the order of 1×10−3. All these observations are explained in terms of ambipolar diffusion of the ions (and electrons) from the sheaths, with thicknesses of the Debye shielding distance, of the laser-induced plasmas in their initial stages. The results obtained indicate that in the case of the Si+ ions the main ionization mechanisms were collisional ionization and multiphoton ionization. © 1994 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 8065-8076 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Angle-resolved time-of-flight (ARTOF) distributions of O, Cu, and Nd atoms and of NdO molecules ablated from the alloy Nd1.85Ce0.15CuO4 were measured with a quadrupole mass spectrometer. From these distributions angle-resolved yield (ARY) distributions of the neutrals were obtained. The most probable kinetic energy was irrespective of the type of neutral approximately 2.3 eV. The experimental ARTOF spectra were fitted quite well with theoretical Maxwell–Boltzmann (FMB) distributions superimposed onto angle-dependent flow-velocity contributions. The temperatures and Mach numbers associated with these fits were about 1.20×103 K and 4.9, respectively, irrespective of the type of atom considered. The experimental ARY distributions were fitted with cosp θ distributions, where p≈6. This p value was much lower than expected from the FMB distributions. The results are discussed in terms of explosive surface evaporation followed by collisional modification in the ablation-induced plasmas of the nascent ARTOF and ARY distributions and in terms of explosive volume evaporation. Additional contributions to the experimental ARTOF and ARY distributions with respect to the fits are ascribed to additional thermal mechanisms. © 1994 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 315-322 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Sputtering of Si in a Cl2 environment by Ar+ and Xe+ ions with energies down to 75 eV has been investigated. Mass spectra and time-of-flight distributions of the sputtered species have been measured. Under 75-eV Ar+-ion bombardment of the Si target, SiCl, SiCl2, SiCl3, and/or SiCl4 are sputtered. When increasing the ion energy the SiCl4 contribution decreases in comparison with SiCl. This is caused by the fact that the newly formed Si-Cl compounds are sputtered at a high rate compared to the rate of SiCl4 formation. Time-of-flight distributions indicate that under 100-eV Ar+-ion bombardment the species are not sputtered by a collision-cascade mechanism. The spectra can be fitted by Maxwell–Boltzmann distributions at a high (〉2000 K) temperature. Increasing the Ar+-ion energy to approximately 250 eV the time-of-flight spectra of the sputtered species change from Maxwell–Boltzmann-like into spectra as expected for a collision-cascade mechanism. For low-energy Xe+ ion bombardment the sputtered species also show Maxwell–Boltzmann time-of-flight distributions. The change from Maxwell–Boltzmann to collision-cascade distributions occurs at higher ion energies than for Ar+-ion bombardment. The results obtained for low ion energies are discussed in terms of evaporation from an ion-induced hot spot.
    Type of Medium: Electronic Resource
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