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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 361 (1968), S. 328-332 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The systems RbCl—AlCl3 and CsCl—AlCl3 have been subjected to a thermal examination up to about 65 Mol-% alkali chloride. The existence of the compounds RbAlCl4 and CsAlCl4 has been shown.As KENDALL and coworkers in the systems NaCl—AlCl3 and KCl—AlCl3 found a miscibility gap below about 18 mol-% alkali chloride, we did an analogous observation in the now investigated systems.
    Notes: Die Systeme RbCl—AlCl3 und CsCl—AlCl3 wurden bis etwa 65 Mol-% Alkalichlorid thermisch untersucht. Es wurden die Verbindungen RbAlCl4 (c) und CsAlCl4 (c) gefunden. Wie KENDALL und Mitarbeiter in den Systemen NaCl—AlCl3 und KCl—AlCl3 fanden, gibt es auch in den beiden untersuchten Systemen eine Mischungslücke bis etwa 18 Mol-% Alkalichlorid.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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