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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 569-577 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Surface preparation of aluminium alloy adherends is designed to minimize the influence of organic contaminant on the durability of epoxy adhesive bonds. The organic contaminant molecules have the potential to inhibit the bonding of the adhesive with the surface oxide on the adherend. X-ray photoelectron spectroscopy (XPS) shows that a freshly exposed aluminium surface quickly adsorbs over ten atomic layers of organic contaminant. Models to fit XPS data measured at various specimen take-off angles indicate that this contaminant is not adsorbed uniformly. Experiments show that for mechanically prepared adherends treated with an organosilane coupling agent, the bond durability depends strongly on the contaminant concentration and the time of administration during the preparation sequence. The observed variations in bond durability can be explained in terms of inhomogeneities in the strength of adhesion between the adhesive and the metal oxide.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 583-590 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A traditional organosilane coupling agent, γ-glycidoxypropyl trimethoxysilane (γ-GPS), was compared with a series of phosphonate hydration inhibitors in the role as metal pretreatments for adhesive bonding. The bond durability of epoxy adhesive-bonded double cantilever beam specimens in hydrothermal environments was assessed where the aluminium adherend had been pretreated with either class of compound. The performance of the compounds is related to the structure of the adsorbed film on the metal substrate and its subsequent interaction with the epoxy adhesive in the bonded system. These assessments were conducted using XPS and Fourier transform infrared spectroscopy (FTIR) analysis of the deposited films and XPS analysis of failed bond specimens to determine the zone of fracture. The bond failure mechanisms are discussed in terms of a simple bond degradation model.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 293-305 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Small additions of nickel chloride to salt solution significantly reduce the corrosion of aluminium alloys. Films produced in these solutions produce a microrough topography which may be suitable for adhesive bonding. Techniques such as XPS, SEM, FTIR and SIMS were used to investigate the properties of the films. The results established that nickel is incorporated in the outer layer of a hydrated aluminium oxide film and is responsible for altering the film growth mechanism. Boeing wedge tests were conducted to assess the relative durability of bonds with adherends pretreated in the salt solutions. The durability performance of the film as a surface treatment for adhesive bonding compared favourably with the Forest Products Laboratory chromate etch. A comparison of the nickel salt treatment with a sodium chloride solution treatment indicated that durability differences were related to their respective hydrated oxide structures.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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