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  • 1
    Electronic Resource
    Electronic Resource
    Hydroxylation and dehydroxylation at Cu(III) surfaces
    Amsterdam : Elsevier
    Chemical Physics Letters 66 (1979), S. 340-343 
    Details
    ISSN: 0009-2614
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0009-2614(79)85030-7
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  • 2
    Electronic Resource
    Electronic Resource
    Specific role of transient O − (s) at Mg(0001) surfaces in activation of ammonia by dioxygen and nitrous oxide (1986)
    [s.l.] : Nature Publishing Group
    Nature 319 (1986), S. 206-208 
    Details
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] It is important to establish whether the Oxygen generated in the act of dissociative chemisorption of nitric oxide, that is, a short-lived species O(s), has any specific chemical reactivity that distinguishes it from the thermodynamically more stable surface Oxide' species, O2(a), which was ...
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1038/319206a0
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  • 3
    Electronic Resource
    Electronic Resource
    Magnetocaloric effect in ordered double-perovskite Ba $_\mathsf{2}$ FeMoO $_\mathsf{6}$ synthesized using wet chemistry (2004)
    Springer
    The European physical journal 41 (2004), S. 213-217 
    Details
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. Double perovskite Ba2FeMoO6 has been prepared by a wet chemistry method and its magnetocaloric effect has been studied. The Ba2FeMoO6 sample, consisting of crystallites with diameter of 130 nm and average aspect ratio of 15, exhibits a sharp magnetic transition. The maximum of the magnetic entropy change peaks at its Curie temperature (340 K), and a large magnetic entropy change ( $\sim$ 1.54 J/kg K, or $\sim$ 0.081 J/mol (atoms) K) is obtained upon 10 kOe applied magnetic field change. For comparison, the magnetic properties of Ba2FeMoO6 prepared by a conventional solid-state reaction was also investigated.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1140/epjb/e2004-00312-9
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  • 4
    Electronic Resource
    Electronic Resource
    Preparation and characterization of rare earth orthovanadates for propane oxidative dehydrogenation (1996)
    Springer
    Catalysis letters 37 (1996), S. 241-246 
    Details
    ISSN: 1572-879X
    Keywords: rare earth orthovanadates ; citrate method ; propane oxidative dehydrogenation ; redox property
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract High purity rare earth orthovanadates (REVO4), YVO4, LaVO4, CeVO4, NdVO4, SmVO4 and EuVO4, were prepared by the citrate method. XRD, FT-IR, LRS and TPR techniques were employed to characterize these orthovanadates. The catalytic performance of SmVO4, LaVO4 and YVO4 in the oxidative dehydrogenation of propane can compete with that of Mg3V2O8. The selectivity of propene over CeVO4, NdVO4 and EuVO4 was relatively lower. The correlation between the reducibility and the selectivity of the catalysts implied that the V4+/V3+ couple might be involved in the dehydrogenation process.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00807761
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  • 5
    Electronic Resource
    Electronic Resource
    Methane activation over unsupported and La2O3-supported copper and nickel catalysts (1996)
    Springer
    Catalysis letters 36 (1996), S. 159-163 
    Details
    ISSN: 1572-879X
    Keywords: methane activation ; Cu/La2O3 and Ni/La2O3 catalysts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Methane was pulsed over pure CuO and NiO as well as Cu/La2O3 and Ni/La2O3 catalysts at 600° C. Results indicate that the mechanisms for methane activation over copper and nickel are quite different. Over CuO, methane is converted to CO2 and H2O, most likely via the combustion mechanism; whereas metallic copper does not activate methane. Over NiO in the presence of metallic nickel sites, methane activation follows the pyrolysis mechanism to give CO, CO2, H2 and H2O. Similar results were obtained over the Cu/La2O3 and Ni/La2O3 catalysts. XRD investigations indicate that copper and nickel existed as CuLa2O4 and LaNiO3 respectively in the La2O3-supported catalysts. The effect of La2O3 on the activation of methane is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00807613
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  • 6
    Electronic Resource
    Electronic Resource
    An ab initio study of methane activation on lanthanide oxide (1997)
    Springer
    Catalysis letters 49 (1997), S. 53-58 
    Details
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Ab initio MP2 calculations have been carried out to study the activation of methane on lanthanide oxide La2O3. O- and O2 2- are assumed to be the active species on the oxide surface. The possible roles of O2- and O2 4- on the oxide surface in C-H bond activation are also investigated. It is shown that the CH4 oxidative dehydrogenation occurs much more readily on O- and O2 2- than on O2- and O2 4-. The results indicate that O- and O2 2- are the active species and therefore support the O- and O2 2- mechanisms assumed for the reactions. The promoter compound containing Br- is found to be favorable for the methane activation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1019040902099
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  • 7
    Electronic Resource
    Electronic Resource
    The activation of O2 and the oxidative dehydrogenation of C2H6 over SmOF catalyst (1996)
    Springer
    Catalysis letters 40 (1996), S. 101-104 
    Details
    ISSN: 1572-879X
    Keywords: ethane oxidative dehydrogenation ; O2 activation ; SmOF ; dioxygen species and mono-oxygen species
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The activation of O2 over SmOF was studied by in situ laser Raman spectrometry and temperature programmed desorption (TPD). When the hydrogen- and helium-treated (1 h for each gas at 973 K) SmOF sample was cooled to 303 K in oxygen, Raman bands which correspond to the existence of O 2 2− , O 2 n− (2 〉n 〉 1), O 2 − and O 2 δ- (1 〉δ 〉 0) species were observed. From 303 to 973 K, there was no O2 desorption but the Raman bands observed at 303 K reduced in intensity and vanished completely at 973 K, even though the sample was under an atmosphere of oxygen. We suggest that as the sample temperature increased, dioxygen species were converted to mono-oxygen species such as O− which were undetectable by Raman spectrometry. O2 desorption occurred above 973 K, giving a TPD-peak at 1095 K. When C2 H6 was pulsed over the sample pretreated with oxygen and helium at 973 K, C2H4 selectivity was 91.8%. We conclude that the mono-oxygen species is responsible for the oxidative dehydrogenation of ethane to ethene.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00807464
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  • 8
    Electronic Resource
    Electronic Resource
    Pulse studies of CH4 interaction with NiO/Al2O3 catalysts (1994)
    Springer
    Catalysis letters 27 (1994), S. 199-206 
    Details
    ISSN: 1572-879X
    Keywords: pulse reaction ; NiO/Al2O3 catalysts ; methane activation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Pulse studies of the interaction of CH4 and NiO/Al2O3 catalysts at 500°C indicate that CH4 adsorption on reduced nickel sites is a key step for CH4 oxidative conversion. On an oxygen-rich surface, CH4 conversion is low and the selectivity of CO2 is higher than that of CO. With the consumption of surface oxygen, CO selectivity increases while the CO2 selectivity falls. The conversion of CH4 is small at 500°C when a pulse of CH4/O2 (CH4∶O2=2∶1) is introduced to the partially reduced catalyst, indicating that CH4 and O2 adsorption are competitive steps and the adsorption of O2 is more favorable than CH4 adsorption
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00806993
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  • 9
    Electronic Resource
    Electronic Resource
    Oxidative coupling of methane over LaF3/La2O3 catalysts (1994)
    Springer
    Catalysis letters 23 (1994), S. 377-386 
    Details
    ISSN: 1572-879X
    Keywords: Oxidative coupling of methane ; LaF3 ; La2O3 ; rhombohedral LaOF
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract We studied the oxidative coupling of methane over the LaF3/La2O3 (50∶50) catalyst. The catalyst was found active even at 873 K. At 1023 K, the C2 yield was 12.7% at 26.0% CH4 conversion and 49.1% C2 selectivity. It was found to be stable and had a lifetime not less than 50 h at 1023 K. The catalyst was effective in C2H6 conversion to C2H4. XRD results indicated that the catalyst was mainly rhombohedral LaOF. It is suggested that the catalyst has ample stoichiometric defects and generates active oxygen sites suitable for methane dehydrogenation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00811372
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  • 10
    Electronic Resource
    Electronic Resource
    Pulse study of methane partial oxidation to syngas over SiO2-supported nickel catalysts (1996)
    Springer
    Catalysis letters 41 (1996), S. 159-163 
    Details
    ISSN: 1572-879X
    Keywords: methane oxidation ; syngas ; SiO2-supported nickel (Ni/SiO2) ; deuterium isotope effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reaction behaviors of CH4/O2 (2/1) with unreduced and reduced SiO2-supported nickel (10 wt% metal) catalysts were investigated in a pulse micro-reactor at temperatures ranging from 600 to 800° C. In the interaction of CH4/O2 with unreduced NiO/SiO2, the products are exclusively CO2 and H2O at or below 700°C. At 800° C, besides CO2 and H2O, CO and H2 are formed. The reactivity at 800°C can be ascribed to the net generation of metallic nickel site at this temperature. In the reaction of CH4/O2 over reduced Ni/SiO2, the main products are CO and H2 with CO2 and H2O being the minor ones. The results indicate metallic nickel is the active site for methane partial oxidation to syngas. Normal deuterium isotope effects of similar magnitude were observed on the overall, as well as on the CO and CO2 formation reactions with insignificant change in the product selectivities when CD4 was used instead of CH4, indicating that methane dissociation is a key step and that CO and CO2 are formed via some common intermediates which are subject to kinetic deuterium isotope effect. The results of deuterium isotope effects can be reasonably explained based on the methane pyrolysis mechanism.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00811484
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