ISSN:
1434-1948
Keywords:
Rhenium
;
N Ligands
;
Nonlinear optics
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Carbonylrhenium bromide complexes fac-Br(OC)3ReL2 (3a,b, 4a,b) and cis-Br(OC)4ReL (5a,b) with conjugated pyridines L = Fc-CH=CH-p-C5H4N (1a), Fc-CH=CHC(CH3)=CHCH=CHCH=C(CH3)CH=CH-p-C5H4N (1b), 1,1′-Fc(-CH=CH-p-C5H4N)2 (1c), p-Me2N-C6H4-CH=CHCH=CH-p-C5H4N (2a), and p-Me2N-C6H4-CH=CHC(CH3)=CHCH=CHCH=C(CH3)-CH=CH-p-C5H4N (2b) have been synthesized. The structures of 4a and 5a have been determined by X-ray diffraction analysis. Compound 4a exhibits a remarkable quadratic hyperpolarizability.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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