ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The PMR spectra of eight compounds R3GeCH=CH2, where R=CH3, Br, Cl; (C2H5)2Ge(CH= CH2)2, and R3GeCH2CH=CH2, where R=CH3, C2H5, Br, Cl, were obtained. 2. For the compound R3MCH= CH2, where R= CH3, Cl, while M= Si or Ge, the contributions of the magnetic anisotropy and the electric field of the substituents to the chemical shifts of the vinyl protons were calculated, which permitted an isolation of the effect of dπ−pπ interaction, which is more substantial in vinylsilanes. 3. The chemical shifts of the protons of allyl groups and substituents were analyzed from the standpoint of the inductive effect and dπ−pπ ininteraction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00907592
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