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  • 1
    Electronic Resource
    Electronic Resource
    PVC miniemulsion polymerization. I. Origin of droplet families (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2923-2930 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A soap/alcohol miniemulsion in combination with an homogenized mixture of monomer and initiator is utilized to generate PVC plastisol. Droplet distributions generated consist of two distinct types. Judicious control of soap-to-alcohol ratio allows control of the number and size of the smaller droplet family; homogenization and initiator water solubility affect the other. Final latex particle distribution may be unimodal or bimodal depending upon manipulation of these factors.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170221115
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    PVC miniemulsion polymerization II. Particle and droplet growth as a function of conversion (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2931-2939 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Growth of two droplet families and a polymer seed family as a function of percent monomer conversion in PVC miniemulsion synthesis demonstrates that polymerization in droplets predominates to ∼ 30-40% conversion, whereupon polymerization of seed becomes favored. This difference appears to be due to a liquid-to-solid phase change in the forming particles during the course of polymerization.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170221116
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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