Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
117 (2002), S. 3711-3714
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The optical response of Li4+ and Li7+ exhibits three large maxima at photon energies between 1.9 and 3.6 eV, on which a fine structures could be resolved that has a peak to peak distance of about 30–40 meV. A high level ab initio calculation of Li4+ shows that this feature is due to vibrational structure of the excited electronic state. It is pointed out that the lifetime of the excited states exhibits a dramatic shortening with increasing particle size. © 2002 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1493193
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