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  • 1
    Electronic Resource
    Electronic Resource
    Rotational Transitions in Neopentyl Alcohol and Neopentyl Glycol (1966)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 70 (1966), S. 3738-3740 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100883a504
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  • 2
    Electronic Resource
    Electronic Resource
    FLOTATION EQUILIBRIUM IN THE ULTRACENTRIFUGE (1962)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 66 (1962), S. 1945-1947 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100816a032
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  • 3
    Electronic Resource
    Electronic Resource
    Der Einfluß von oberflächenaktiven Substanzen auf die Sorption eines kationischen Polymeren durch Keratinsubstrate (1978)
    Springer
    Colloid & polymer science 256 (1978), S. 390-390 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01544394
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  • 4
    Electronic Resource
    Electronic Resource
    Mechanical behavior of polycarbonates (1961)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 54 (1961), S. S56 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1961.1205416041
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  • 5
    Electronic Resource
    Electronic Resource
    The stiffness of ethylene copolymers (1962)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 60 (1962), S. S36 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1962.1206016922
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  • 6
    Electronic Resource
    Electronic Resource
    Mechanical behavior of poly(stilbestrol carbonate) (1962)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 62 (1962), S. S171 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1962.1206217467
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  • 7
    Electronic Resource
    Electronic Resource
    Glass transitions of organic compounds. III. Cellulose substrate technique and aliphatic alcohols (1979)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 716-721 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The cellulose blotter/torsion pendulum technique used for the determination of relaxations that occur in low molecular weight compounds, oligomeric materials, and amorphous polymers is discussed. The glass transition temperature of a number of aliphatic alcohols and hydrocarbons have been determined and correlated with a method proposed by Gorskii in 1934. The glass transition temperature and molecular weight of these compounds follow the relationship Tg = BMa rather than Tg = Tg(∞) - K/M. Although differences exist between the primary, secondary, and tertiary alcohols, they appear to follow a similar general pattern. In contrast, the hydrocarbons investigated have markedly different behavior.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760191011
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  • 8
    Electronic Resource
    Electronic Resource
    Glass transitions in ethylene copolymers and vinyl homopolymers and copolymers (1962)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 57 (1962), S. 483-498 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In ethylene copolymers isolated—CH2CHR—CH2— groups undergo a glass transition at about -10 to -50°C., the exact temperature depending upon the nature of R. For any given copolymer the temperature of the transition remains reasonably constant over a broad composition range at high ethylene contents. At high comonomer content the transition rises with composition along the line drawn between the glasstransition temperature of polyethylene and that of the homopolymer of the comonomer in question. A second glass transition is also observed in ethylene copolymers at about -125°C. over the whole composition range. This transition corresponds to motion of —CH2— sequences of three to five or more in the main chain. The temperature position of this transition is usually independent of the nature of the rest of the chain. The behavior of ethylene copolymers is quite different from that of normal vinyl copolymers, where only a single glass transition is observed for each composition and where the temperature position of the transition changes uniformly with composition along the line drawn between the glass transitions of the respective homopolymers. It is concluded that the motions involved in the glass transitions of the main chain —CH2— sequences and of isolated —CH2CHR—CH2— groups in ethylene copolymers are localized, involving only a few carbon atoms. In the case of the normal vinyl copolymers, on the other hand, the motion at the transition appears to be a long-range motion involving a great many chain carbon atoms and cooperative motion of the pendent groups. This change in the nature of the motion involved at the glass transition in going from high ethylene content copolymers to low ethylene content or vinyl copolymers appears to arise because of steric hindrance and/or restrictive dipolar forces between the pendent groups of the —CH2—CHR—CH2— segments in those cases were they are not isolated from each other. Finally, it is concluded that all vinyl homopolymers would have glass transitions in the -10 to -50°C. range if steric hindrance between the side groups did not occur. It is shown that as the pendent group becomes less bulky or is further separated from the main chain by —CH2—groups the glass transition temperature decreases presumably towards the -10 to -50° range characteristic of the transition of isolated —CH2CHR—CH2— groups.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1962.1205716538
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  • 9
    Electronic Resource
    Electronic Resource
    Some considerations on nonstationary-state kinetics of vinyl polymerizationPresented in part at the 142nd meeting of the American Chemical Society, Atlantic City, N. J., September 1962. (1964)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 2 (1964), S. 3103-3111 
    Details
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: When primary free radicals approach their stationary-state concentration at a rate which is of the same order of magnitude as that with which chain radicals approach their stationary-state concentration, the familiar nonstationary-state equation relating the chain radical concentration to the time of reaction is no longer adequate. An accurate mathematical description of this situation has now been obtained which not only allows one to examine the dependence of chain radical concentration on the reaction time but also provides a basis for predicting under what conditions the primary radicals will be slow to approach a steady state. On the basis of these results the degree of error which is introduced into measurements of termination rate constants has been calculated and an experimental approach for measuring specific rate constants of chain initiation has been suggested.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1964.100020710
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  • 10
    Electronic Resource
    Electronic Resource
    Glass transitions of polyoxetanes (1964)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 2 (1964), S. 5017-5023 
    Details
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Glass transition data of polyexetanes suggest that the responsible segmental chain motions are rather short range in nature. The incorporation of three different structural features within the repeat unit of a polyoxetane results in three separate and independent transition temperatures. The temperature positions of the transitions arising from different structures within the chain are essentially the same as observed in other polymers with a similar structural element. Structural groups and their corresponding transitions which were studied in combination are: —CH2—CH2—CH2 at -125°C., —CH2—O—CH2— at -50 to -70°C., and —CH2CHCH3—CH2— or —O—CHCH3—CH2— at -20 to -30°C.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1964.100021128
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