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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 3377-3383 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In the photocharging process, aerosol particles become electrically charged through interaction with high-energy photons, e.g., ultraviolet (UV) irradiation. Photon adsorption by particles leads to electron emission and, as a result, particles become positively charged. While maximum achievable charges have been described in previous studies of dependency on particle and irradiation parameters, the influence of photoemitted charges on the charging process was not taken into account. In this work it is shown that such charges interact with the particles, which heavily influences the entire process. This complex process (the charging of particles positively by photons and simultaneously negatively by ions) is described in this work by a set of differential equations. These differential equations are solved numerically and, with simplifying assumptions, analytically. Multicomponent polydisperse aerosol is considered. As was found by comparing the analytical and numerical solutions, analytical results coincide with numerical ones for a wide range of initial parameters (particle number concentration, diameter). The analytical expressions evaluated allow one to quantify the influence of guiding processes and the limits of the charging process, which is heavily influenced by the previously neglected free ions. Model results explain such phenomena as the experimentally observed decrease in particle charge through the increase in particle number concentration. As a result of this work, the particle charge distribution obtained by the photocharging process can now be considered a known function of aerosol and UV-irradiation parameters. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 4431-4433 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on a method to obtain tailored nanoparticle aggregates of two components in the gas phase. The method is based on the modification of the Brownian collision rate by charging the nanoparticles. Particles of different components are charged oppositely in order to obtain composite nanoparticle aggregates via preferential coagulation. The resulting composite aggregates are uncharged, which allows for their separation from both, charged unaggregated particles and charged aggregates of only one component. The mean size and standard deviation of each particle component can be adjusted by means of differential mobility analysis. Experimental results are presented for composites of PbS and Ag. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 3708-3710 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Arrangements of nanometer-sized particles were obtained on plane oxidized silicon substrates by direct deposition from the gas phase. The particles were attracted onto charge patterns created by contact charging. Monodisperse, singly charged indium aerosol particles with a diameter of 30 nm were used as a test case to illustrate this process. Due to the surface treatment, the deposition is highly selective. We were able to create lines of particles with widths as narrow as 100 nm and several millimeters in length. The resolution of the pattern depends mainly on the surface treatment and the tool geometry. Our approach opens the possibility of creating patterns composed of nanometer-sized particles on a flat substrate surface by the simple transfer of charge patterns, without a lithographical process. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 547-549 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on the synthesis of size-classified PbS nanocrystals by differential mobility analysis of a polydisperse aerosol formed by nucleation and aggregation processes in a furnace reactor. The sublimation temperature employed is below the stoichiometric evaporation temperature, thus enabling direct and simple synthesis by sublimation. The irregularly shaped and amorphous agglomerate particles are then sintered in a second furnace, resulting in the formation of monocrystalline and quasispherical particles with sizes adjustable between 3 and 20 nm and a standard deviation of 1.13. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of nanoparticle research 1 (1999), S. 145-145 
    ISSN: 1572-896X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1572-896X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of nanoparticle research 1 (1999), S. 511-512 
    ISSN: 1572-896X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 13 (1996), S. 327-332 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes the evaluation of the transfer function for the TSI-short differential mobility analyzer (DMA) in the nanometer particle size rang. The TSI-short DMA is identical with the TSI-long DMA (Model 3071) but has shortened inner and outer electrodes and the insulator material Teflon was replaced by black Delin. The DMA transfer function was determined by operating two identical DMAs in series. The DMA was investigated at a sheath to aerosol flow rate ratio of between 10 and 1. Usually for particles above 50 nm the parameters of the assumed triangular transfer function, i.e. height and half-width, approach the ideal values, which depend only on the flow ratio. For particle size below 50 nm the height decreases from 0.9 at 50 nm to 0.18 at 5 nm. The half-width increase from the ideal value 0.1 to about 0.17. The observed changes of the transfer function are due to diffusional effects resulting in losses mainly in the inlet and outlet and also broadening of the aerosol stream inside the DMA. The determined transfer functions were also compared with transfer functions calculated using a theoretical model. The agreement proved to be satisfactory. The half-widths and the transmission efficiencies of the conventional TSI-DMA (Model 3071), TSI-short with Teflon and also black Delin insulator as a function of particle size are compared to demonstrate the improvements in performance.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 7 (1990), S. 250-255 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The bipolar diffusion charging process is studied theoretically for aerosol particles in high purity argon and nitrogen. The Fuchs theory is extended by the incorporation of the free electron charging of the aerosol particles. The ion parameters for positive and negative ions are assumed to be identical. The influence of the free electrons explains the differences between the mean mobility and mean mass of negative and positive ions. The ratio of the electron number concentration to the number concentration of negative ions is used to fit the curves, calculated by the extended model, to the experimentally determined bipolar charge distribution in argon and nitrogen. The extended Fuchs model was found to be rather insensitive to variations in the mobility and mass compared with the model with four different ion parameters. Further experimental studies of the bipolar charge distribution in a gas mixture of pure nitrogen and sulfur hexafluoride, SF6, indicate the importance of the free electrons in the bipolar diffusion charging process.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 10 (1993), S. 33-37 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A scattered light photometer which monitors the particle number concentration of aerosols is described. The photometer measures the scattered light from illuminated submicron particle clouds with known material properties at certain scattering angles. Intensity ratios in combination with the degree of polarization are used to determine the mean particle diameter and the geometric standard deviation of an assumed log-normal particle size distribution. The determination of the particle size distribution is based on an algorithm which compares the measured and calculated (Mie theory) relative intensity quantities described. Furthermore, the particle number concentration is monitored from a single absolute intensity measurement at one scattering angle. In order to obtain quantitative results a spherical particle shape is required.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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