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  • 1
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 1879-1886 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A continuous and stopped flow EPR spectrometer based on a new loop gap resonator operating at X band is described. The important features of the instrument are: (1) very small amounts of material are consumed in both stopped and continuous flow modes of operation, (2) dead times on the order of 4 ms for stopped flow and 1 ms for continuous flow are realized with a very narrow age distribution in the sample compartment, and (3) the dead times and, hence, sample age are highly reproducible and independent of viscosity due to the use of a positive displacement syringe ram. The performance of the instrument is evaluated using the decay of ascorbate radical generated by Ce(iv) oxidation and reduction of nitroxides by ascorbic acid.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 9272-9279 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A method to excite multiquantum transitions in a two-level system by application of continuous irradiation with a four-frequency microwave field is presented. The generated signal is composed of many intermodulation sidebands at different frequencies, which arise from the multiquantum transitions. These processes involve an odd number of photons, that are absorbed from, or emitted to two, three, or four fields. The correspondence between the frequency spectrum of the signal and possible pathways of multiquantum processes is found with recourse to the many mode Floquet theory. The reported experiments demonstrate the multiquantum origin of the detected intermodulation sidebands and their properties. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 4563-4571 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The Bloch equations are applied to describe the response of the two-level system, irradiated with bichromatic microwave field under condition of electron paramagnetic resonance in the wide range of saturation condition and relaxation times. The generation of the intermodulation effects in such systems has been demonstrated. Numerical procedures of solving a set of stiff, nonlinear differential equations are applied. The line shapes of the generated signals have been simulated for different microwave amplitudes and relaxation rates. The dependence of the intermodulation signals on ω2−ω1, the frequency difference between two incident microwave fields, is studied. The influence of a significant saturation factor on this dependence is demonstrated and explained. Then an estimation of the relaxation rates from the intermodulation sidebands is examined on the basis of the classical model. In the case when the frequency separation between two alternating fields is less than relaxation rates, analytical formulas for the intermodulation signals have been found. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 4857-4865 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Instrumentation for remote control of the unloaded quality factor, Q0, of a loop-gap resonator is described. The value of Q0 can be lowered by weak inductive coupling of the resonator to a loop of wire that contains a carbon resistor. Replacement of the resistor by a PIN diode permits remote control. Theoretical analysis and experiments are carried out in a context of electron paramagnetic resonance (EPR) spectroscopy at X band. Equivalent circuits are solved numerically and predicted performance confirmed experimentally. Two applications are demonstrated: (a) superfine control of critical coupling of the incoming transmission line to the resonator in excess of −80 dB, and (b) dynamic Q spoiling for reduction of the dead time after a microwave pulse. Possible degradation of EPR system performance by shot noise from the PIN diode is considered. Scant literature suggests that it is very low, and noise from this source could not be detected experimentally. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 3037-3041 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Traditional methods of measuring total body water and fat content of animals that require sacrificing specimens are generally unacceptable when endangered species, or large animal sizes, or humans are involved. These methods are also unsuitable for following changes of fat and water content in individuals. An alternative method, based on the nonresonant absorption of a rf electromagnetic field has been used for constructing a new body composition analyzer. As the electrical conductivity of lipids is approximately 20 times lower than that of lean tissues, the rf power absorbed by the animal provides information which enables one to calculate the lean body mass and total body water. The new instrument measures rf power absorbed by an animal by measuring the quality factor (Q) of the resonant circuit with an animal placed inside the coil. Numerical calculations of the rf power absorbed by a cylindrical object containing 0.9% NaCl aqueous solution have also been performed. Experimental values confirmed the calculated dependence of the absorbed power on the cylinder radius. The device built has been calibrated on 9 males and 11 females of laboratory mice. The amount of lipids was then measured by ether extraction. The relation between instrument reading, which is proportional to the power absorption, and lean body mass (LBM) or water mass (WM) was linear and highly significant: the simple regression coefficients of determination were 0.983 for LBM, and 0.990 for WM (p〈0.001). It has been found that for an individual animal with a body mass ranging from 15.9 to 40.7 g, the accuracy of measurement was ±1.6 g for LBM and ±1 g for WM. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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