ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Electronic absorption spectra of radical cations generated by steady-state and pulse radiolysis from a series of α,ω-diaminoalkanes (R2N(CH2)nNR2; n = 1-6, R = CH3 or C2H5), 1,4-dimethylpiperazine and 1,4-diazabicyclo [2.2.2] octane (DABCO) were measured. In some cases spectral evidence was obtained for an interaction between the nitrogen atoms leading to charge delocalization in the radical cation. A delayed formation of radical cations was associated with a conformational change necessary for achieving the most stable structure having a favourable conformation for charge delocalization.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610030909
Permalink