ISSN:
1573-4889
Keywords:
nickel
;
oxidation
;
transport
;
tracer
;
duplex scale
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract Experimental techniques have been developed for determining Ni63 and O18 tracer distributions in NiO scales ranging in thickness from ∼0.1 to 100 μ. These have been used to investigate Ni and O transport in scales on {100} Ni crystals and polycrystalline Ni in the temperature range 500–1300° C. NiO grown on {100} Ni crystals at 1000°C was uniform and compact and grew by the bulk diffusion of Ni in NiO by a vacancy mechanism. At temperatures below 800°C the principal transport mechanism was short-circuit diffusion of Ni in NiO. At all temperatures short-circuit diffusion of oxygen contributed to scale growth on polycrystalline Ni and was responsible for growth of the inner layer of duplex scales. The oxygen diffusion paths are believed to be micro-cracks induced by growth stresses.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00812776
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