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  • 1
    ISSN: 1432-0789
    Keywords: Key words Soluble organic nitrogen ; Mineral nitrogen ; Potentially mineralisable nitrogen ; Cultivation ; Grassland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  This study evaluated the effect of cultivation and reseeding on the distribution and fate of soil mineral N (SMN), soluble organic N (SON) and potentially mineralisable N (PMN) in the soil profile of two long-term grasslands in the UK. Cultivation and reseeding significantly increased the total soluble N concentration (SMN plus SON) of the soil profile (0–90 cm), with over 50 mg SON kg–1 observed. By contrast, the PMN pool was unaffected by cultivation and declined with increasing soil depth. The flush in SON and SMN observed in both soils disappeared within 1 year following cultivation. The fate of SON appeared to be dependent on soil type, with considerably more movement to deeper layers apparent in the profile of a silty clay loam (30% clay) than in a clay loam (49% clay). Mineralisation and/or immobilisation of SON in the topsoil probably accounted for the changes observed in the SON content of the clay loam. SON is an important N pool in grassland soils and cultivation has a significant impact on its release. Measurements of SON should therefore be included in studies of N cycling in agricultural cropping systems, so that full account may be taken of its potential as a source or sink of mobile N.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0789
    Keywords: Key words Dissolved organic nitrogen ; Soluble organic nitrogen ; Nitrogen transformations ; Nitrogen loss ; Leaching
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  The existence of soluble organic forms of N in rain and drainage waters has been known for many years, but these have not been generally regarded as significant pools of N in agricultural soils. We review the size and function of both soluble organic N extracted from soils (SON) and dissolved organic N present in soil solution and drainage waters (DON) in arable agricultural soils. SON is of the same order of magnitude as mineral N and of equal size in many cases; 20–30 kg SON-N ha–1 is present in a wide range of arable agricultural soils from England. Its dynamics are affected by mineralisation, immobilisation, leaching and plant uptake in the same way as those of mineral N, but its pool size is more constant than that of mineral N. DON can be sampled from soil solution using suction cups and collected in drainage waters. Significant amounts of DON are leached, but this comprises only about one-tenth of the SON extracted from the same soil. Leached DON may take with it nutrients, chelated or complexed metals and pesticides. SON/DON is clearly an important pool in N transformations and plant uptake, but there are still many gaps in our understanding.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Soil use and management 14 (1998), S. 0 
    ISSN: 1475-2743
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract. Atmospheric nitrogen (N) makes a significant contribution to the N inputs to agricultural systems and is a major eutrophying and acidifying input to natural and semi-natural ecosystems. We have estimated the nitrogen deposited to arable land at Rothamsted and at two Nitrate Vulnerable Zones (NVZs) in the UK, Lichfield and the River Waveney. Using the SUNDIAL N cycle model calibrated against measured soil mineral N and leaching losses at Rothamsted, we have calculated the contribution of deposited N to nitrate leaching under a range of crops growing on the major soil series in the NVZs. Approximately 44, 46 and 28 kg N/ha per yr are deposited to arable land around Rothamsted and in the Lichfield and Waveney NVZs, respectively. Most of this is dry-deposited in oxidized forms: nitrogen dioxide and nitric acid are the main components, arising mostly from industry, home heating and vehicle emissions. SUNDIAL predicts that current total leaching losses from arable crops average 39 kg N/ha per yr in the Lichfield NVZ anti 22 kg/ha per yr in the Waveney NVZ. Atsmospheric N contributes about 28% of the N leached from arable land in the Lichfield NVZ and 17% in the Waveney NVZ, a very significant amount. There is little variation in total leaching or the atmospheric contribution to it between soil series within each NVZ, but much variation with crop type and the weather: atmospheric N can comprise over 40% of the N leached under spring cereals in some years.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Soil use and management 2 (1986), S. 0 
    ISSN: 1475-2743
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Soil samples have been taken periodically from unlimed plots of the 130-year-old Park Grass Experiment and from the 100-year-old Geescroft Wilderness at Rothamsted. Changes in the pH of the samples show how acidification has progressed. The soils are now at, or are approaching, equilibrium pH values which depend on the acidifying inputs and on the buffering capacities of the soils. We have calculated the contributions to soil acidification of natural sources of acidity in the soil, atmospheric deposition, crop growth and nutrient removal, and, where applicable, additions of fertilizers. The relative importance of each source of acidification has changed as the soils have become more acid. Acid rain (wet deposited acidity) is a negligible source, but total atmospheric deposition may comprise up to 30% of acidifying inputs at near neutral soil pH values and more as soil pH decreases. Excepting fertilizers, the greatest causes of soil acidification at or near neutral pH values are the natural inputs of H+ from the dissolution of CO2 and subsequent dissociation of carbonic acid, and the mineralization of organic matter.Under grassland, single superphosphate and small amounts of sodium and magnesium sulphates have had no effect on soil pH, whilst potassium sulphate increased soil acidity slightly. All of these effects are greatly outweighed under grassland, however, by those of nitrogen fertilizers. Against a background of acidification from atmospheric, crop and natural inputs, nitrogen applied as ammonium sulphate decreased soil pH up to a maximum of 1.2 units at a rate in direct proportion to the amount added, and nitrogen applied as sodium nitrate increased soil pH by between 0.5 and 1 unit.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Soil use and management 1 (1985), S. 0 
    ISSN: 1475-2743
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract. Rainfall has become less acid at Rothamsted and Saxmundham over the period 1969–83. The pH of rain at these two sites has increased from 4.4–4.6 to about 4.8–4.9; at Woburn it has remained approximately constant at 4.4–4.6. Amounts of NH4-N and NO3-N deposited at present are 10–15 and 5–10 kg ha−1 a−1 respectively. They have been increasing at Rothamsted and Woburn. Some 50–60 kg ha−1 a−1 of Cl and 25–35 kg ha−1 a−1 of SO4-S are presently deposited. Deposition of non-sea Cl and SO4-S has been increasing markedly at all three sites. Non-sea salts comprise 35% of the total salt deposition near the coast at Saxmundham, 58% inland at Rothamsted and Woburn.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: We have examined the effect that acid deposition and other sources of acidity have had over the last 110–140 years on soil under woodland (Broadbalk and Geescroft Wildernesses) and grassland (Park Grass) comprising some of the Classical Experiments at Rothamsted Experimental Station. Changes in soil chemistry have been followed by analysing some of the unique archive of stored samples for pH, water-soluble and exchangeable base cations, aluminium, iron and manganese, exchangeable acidity, cation exchange capacity (CEC) and soluble anions. Proton balances and historical data show the importance of acid deposition to acidification and concomitant changes in the chemistry of the soil. The pH of the surface soil of Geescroft Wilderness has fallen from 6.2 to 3.8 since 1883. The decrease in the pH of the unlimed, unfertilized plot on Park Grass was less over a similar period (from pH 5.2 to 4.2), illustrating the significant effect of the woodland canopy on the interception of acidifying pollutants. The effect of increasing acidity on the soil chemistry of Geescroft Wilderness is seen in its decreasing base saturation and CEC, with base cations moving down the soil profile. Clay minerals are being irreversibly weathered, and Mn and Al progressively mobilized, so that today Al occupies 70% of the exchange complex in the surface soil. Even with present reductions in sulphur deposition critical loads for sulphur, nitrogen and acidity are still exceeded. Such semi-natural ecosystems are unsustainable under the current climate of pollution.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: We used the wavelet transform to quantify the performance of models that predict the rate of emission of nitrous oxide (N2O) from soil. Emissions of N2O and other soil variables that influence emissions were measured on soil cores collected at 256 locations across arable land in Bedfordshire, England. Rate-limiting models of N2O emissions were constructed and fitted to the data by functional analysis. These models were then evaluated by wavelet variance and wavelet correlations, estimated from coefficients of the adapted maximal overlap discrete wavelet transform (AMODWT), of the fitted and measured emission rates.We estimated wavelet variances to assess whether the partition of the variance of modelled rates of N2O emission between scales reflected that of the data. Where the relative distribution of variance in the model is more skewed to coarser scales than is the case for the observation, for example, this indicates that the model predictions are too smooth spatially, and fail adequately to represent some of the variation at finer scales. Scale-dependent wavelet correlations between model and data were used to quantify the model performance at each scale, and in several cases to determine the scale at which the model description of the data broke down. We detected significant changes in correlation between modelled and predicted emissions at each spatial scale, showing that, at some scales, model performance was not uniform in space. This suggested that the influence of a soil variable on N2O emissions, important in one region but not in another, had been omitted from the model or modelled poorly. Change points usually occurred at field boundaries or where soil textural class changed.We show that wavelet analysis can be used to quantify aspects of model performance that other methods cannot. By evaluating model behaviour at several scales and positions wavelet analysis helps us to determine whether a model is suitable for a particular purpose.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 51 (2000), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The usefulness of stored soils from long-term experiments is often questioned because of changes that might occur during storage. We examined changes during long-term storage (8–69 years) in the chemical properties of soils with a range of pH values (3.4–8.1 in water) from woodland and grassland experiments at Rothamsted Experimental Station in the UK. No significant changes during storage were measured for total C and N. Large but erratic changes in exchangeable Na+ content between 1959 and 1991 were probably caused by contamination of the 1959 samples by perspiration and from sodium-based glassware. Exchangeable K+ increased during storage but only by a small amount. Small changes in exchangeable Ca2+ and Mg2+ were measured in some samples but not in others. Generally the amount of exchangeable cations increased slightly during storage. This is probably linked to the decreases of 〈inlineGraphic alt="leqslant R: less-than-or-eq, slant" extraInfo="nonStandardEntity" href="urn:x-wiley:13510754:EJSS307:les" location="les.gif"/〉 0.4 units in the pH of acid soils, which we attribute to the hydrolysis of approximately 0.25% of the exchangeable Al3+. A doubling of the amount of exchangeable Mn2+ during storage for 32 years was probably caused by re-equilibration of Mn species. The most practicable way to prepare soil samples for long-term storage is to dry them in air. However, those who study changes in soil by re-analysing samples of the soil stored for a long time must (i) use the same methods of analysis, or (ii) demonstrate that different methods lead to the same results, and (iii) know what changes can arise during storage.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    European journal of soil science 48 (1997), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Although trade element uptake on and release from solid phases are fundamental controls on the migration of the elements in the environment, the controls are incompletely understood. The extraction of uranium from two soils, both of which have been labelled naturally with uranium, was therefore studied using a cation resin exchange technique. One soil was a peat from the Needle's Eye natural analogue site, Scotland, and the other was a calcareous brown earth from Derbyshire, England. The effects of different exchanging cations, solution pH and the presence of complexing anions (Cl−, CO32−, SO42−) in solution on uranium extraction were assessed. The extraction could be described by a simple, first-order kinetic model with up to three rate constants being identifiable in individual experiments. In both soils no single reaction pathway appeared to dominate, and extraction was slow, with rate constants of 10−3−10−4 h−1 in acid conditions and around 10−6 h−1 in neutral conditions. Half-times for uranium release in the experiments were in the range 30–60 days in acid and around 10 years in neutral conditions; in the field they are therefore expected to be several years at both sites. Incorporation of kinetic factors into a simple one-dimensional migration model illustrates that their overall effect is to retard migration. Ideally, therefore, reaction rates should be taken into account in predictive modelling of element transport.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    European journal of soil science 48 (1997), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The transformations of phyllosilicates and the changes in potassium (K) balances caused by long-term cropping have been examined in soil from the 153-year-old Broadbalk experiment. Samples taken between 1856 and 1987 and kept in archive were fractionated for particle size and analysed for changes in mineralogy by X-ray diffraction and changes in total K of the coarser and fine fractions. These were compared with K balances made from records of cropping and fertilizer application. No change in mica due to cropping and K-depletion could be detected. Deep ploughing after 1925 mixed chlorite from the subsoil into the surface soil, but this had weathered by 1987. Potassium balances did not agree with measured changes in total K presumably because of unquantified uptake of K from the subsoil and poorly quantified K leaching.
    Type of Medium: Electronic Resource
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