ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reduction of acetylated or benzoylated glycosyl halides or selenides with low concentrations of tributylstannane leads to 2-deoxy sugars. An important step in this radical-chain reaction is the cis-selective migration of an ester group. The broad applicability of this method is demonstrated by the synthesis of mono- and dideoxy sugars, of α- and β-deoxy sugars, of deoxypyranoses and deoxyfuranoses, of deoxypentosyl- and -hexosyl carbohydrates.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198819880625
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